Control of Gas Sorption Gate-opening in Solid Solutions of One-dimensional Coordination Polymers

Jun Zhang; Wataru Kosaka; Hitoshi Miyasaka

doi:10.1246/cl.190557

Control of Gas Sorption Gate-opening in Solid Solutions of One-dimensional Coordination Polymers

Jun Zhang, Wataru Kosaka, Hitoshi Miyasaka

Research output: Contribution to journal › Review article › peer-review

7 Citations (Scopus)

Abstract

An isostructural solid solution series of one-dimensional coordination polymers, [(Ru₍₁ ¹x₎Rh_x)₂(2,4,5-Me₃PhCO₂)₄(phz)] (x = 0, 0.1, 0.22, 0.39, 0.55, and 1; 2,4,5-Me₃PhCO₂ ¹ = 2,4,5-trimethylbenzoate; phz = phenazine), was prepared by mixing [Rh₂ ^II,II(2,4,5-Me₃PhCO₂)₄] with [Ru₂ ^II,II(2,4,5-Me₃PhCO₂)₄] in x:(1 ¹ x) reaction ratios, respectively. This series of compounds systematically tunes the gate-opening pressures for the adsorption of CO₂ (195 K) and NO (121 K), suggesting a feasible and simple method to modulate the gate-opening pressures.

Original language	English
Pages (from-to)	1308-1311
Number of pages	4
Journal	Chemistry Letters
Volume	48
Issue number	11
DOIs	https://doi.org/10.1246/cl.190557
Publication status	Published - 2019

Keywords

Gas sorption properties
One-dimensional coordination polymers
Solid solutions

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.190557

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@article{017c0da00af341ab9a0f58495d920454,

title = "Control of Gas Sorption Gate-opening in Solid Solutions of One-dimensional Coordination Polymers",

abstract = "An isostructural solid solution series of one-dimensional coordination polymers, [(Ru(1 1x)Rhx)2(2,4,5-Me3PhCO2)4(phz)] (x = 0, 0.1, 0.22, 0.39, 0.55, and 1; 2,4,5-Me3PhCO2 1 = 2,4,5-trimethylbenzoate; phz = phenazine), was prepared by mixing [Rh2 II,II(2,4,5-Me3PhCO2)4] with [Ru2 II,II(2,4,5-Me3PhCO2)4] in x:(1 1 x) reaction ratios, respectively. This series of compounds systematically tunes the gate-opening pressures for the adsorption of CO2 (195 K) and NO (121 K), suggesting a feasible and simple method to modulate the gate-opening pressures.",

keywords = "Gas sorption properties, One-dimensional coordination polymers, Solid solutions",

author = "Jun Zhang and Wataru Kosaka and Hitoshi Miyasaka",

note = "Funding Information: This work was supported by a Grant-in-Aid for Scientific Research (Nos. 16H02269, 18K19050, 18K05055, 18H05208) from MEXT, Japan, and on Innovative Areas (“π-System Figuration” Area 2601, No. 17H05137) from JSPS, Japan, and Grant Fund for Research and Education of Institute for Materials Research, Tohoku University. J.Z. is thankful for the JSPS KAKENHI (No. 17J02497). Publisher Copyright: {\textcopyright} 2019 Chemical Society of Japan. All rights reserved.",

year = "2019",

doi = "10.1246/cl.190557",

language = "English",

volume = "48",

pages = "1308--1311",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "11",

}

TY - JOUR

T1 - Control of Gas Sorption Gate-opening in Solid Solutions of One-dimensional Coordination Polymers

AU - Zhang, Jun

AU - Kosaka, Wataru

AU - Miyasaka, Hitoshi

N1 - Funding Information: This work was supported by a Grant-in-Aid for Scientific Research (Nos. 16H02269, 18K19050, 18K05055, 18H05208) from MEXT, Japan, and on Innovative Areas (“π-System Figuration” Area 2601, No. 17H05137) from JSPS, Japan, and Grant Fund for Research and Education of Institute for Materials Research, Tohoku University. J.Z. is thankful for the JSPS KAKENHI (No. 17J02497). Publisher Copyright: © 2019 Chemical Society of Japan. All rights reserved.

PY - 2019

Y1 - 2019

N2 - An isostructural solid solution series of one-dimensional coordination polymers, [(Ru(1 1x)Rhx)2(2,4,5-Me3PhCO2)4(phz)] (x = 0, 0.1, 0.22, 0.39, 0.55, and 1; 2,4,5-Me3PhCO2 1 = 2,4,5-trimethylbenzoate; phz = phenazine), was prepared by mixing [Rh2 II,II(2,4,5-Me3PhCO2)4] with [Ru2 II,II(2,4,5-Me3PhCO2)4] in x:(1 1 x) reaction ratios, respectively. This series of compounds systematically tunes the gate-opening pressures for the adsorption of CO2 (195 K) and NO (121 K), suggesting a feasible and simple method to modulate the gate-opening pressures.

AB - An isostructural solid solution series of one-dimensional coordination polymers, [(Ru(1 1x)Rhx)2(2,4,5-Me3PhCO2)4(phz)] (x = 0, 0.1, 0.22, 0.39, 0.55, and 1; 2,4,5-Me3PhCO2 1 = 2,4,5-trimethylbenzoate; phz = phenazine), was prepared by mixing [Rh2 II,II(2,4,5-Me3PhCO2)4] with [Ru2 II,II(2,4,5-Me3PhCO2)4] in x:(1 1 x) reaction ratios, respectively. This series of compounds systematically tunes the gate-opening pressures for the adsorption of CO2 (195 K) and NO (121 K), suggesting a feasible and simple method to modulate the gate-opening pressures.

KW - Gas sorption properties

KW - One-dimensional coordination polymers

KW - Solid solutions

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U2 - 10.1246/cl.190557

DO - 10.1246/cl.190557

M3 - Review article

AN - SCOPUS:85073372027

SN - 0366-7022

VL - 48

SP - 1308

EP - 1311

JO - Chemistry Letters

JF - Chemistry Letters

IS - 11

ER -

Control of Gas Sorption Gate-opening in Solid Solutions of One-dimensional Coordination Polymers

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