Control of interpenetration for tuning structural flexibility influences sorption properties

Sareeya Bureekaew; Hiroshi Sato; Ryotaro Matsuda; Yoshiki Kubota; Raita Hirose; Jungeun Kim; Kenichi Kato; Masaki Takata; Susumu Kitagawa

doi:10.1002/anie.201002259

Control of interpenetration for tuning structural flexibility influences sorption properties

Sareeya Bureekaew, Hiroshi Sato, Ryotaro Matsuda, Yoshiki Kubota, Raita Hirose, Jungeun Kim, Kenichi Kato, Masaki Takata, Susumu Kitagawa

SRIS - SR Core Research Division

Research output: Contribution to journal › Article › peer-review

180 Citations (Scopus)

Abstract

Transforming jungle gyms: Structural flexibility and sorption behavior can be tuned by controlling the degree of interpenetration of 3D porous coordination polymers (PCPs). The architectural connectivity of PCPs, even those that are composed of the same chemical components, has a significant impact on the structural flexibility and sorption behavior, which was confirmed by coincident XRPD/adsorption measurements.

Original language	English
Pages (from-to)	7660-7664
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	42
DOIs	https://doi.org/10.1002/anie.201002259
Publication status	Published - 2010 Oct 11

Keywords

Carbon dioxide
Coordination polymers
Host-guest systems
Hybrid materials
Phase transitions

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10.1002/anie.201002259

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AU - Bureekaew, Sareeya

AU - Sato, Hiroshi

AU - Matsuda, Ryotaro

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AU - Hirose, Raita

AU - Kim, Jungeun

AU - Kato, Kenichi

AU - Takata, Masaki

AU - Kitagawa, Susumu

PY - 2010/10/11

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KW - Carbon dioxide

KW - Coordination polymers

KW - Host-guest systems

KW - Hybrid materials

KW - Phase transitions

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Control of interpenetration for tuning structural flexibility influences sorption properties

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Keywords

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