Convergent and stereoselective method for synthesis of O-linked oxepane ring system by intramolecular radical cyclization

Makoto Sasaki; Masayuki Inoue; Tetsuji Noguchi; Atsuo Takeichi; Kazuo Tachibana

doi:10.1016/S0040-4039(98)00338-4

Convergent and stereoselective method for synthesis of O-linked oxepane ring system by intramolecular radical cyclization

Makoto Sasaki, Masayuki Inoue, Tetsuji Noguchi, Atsuo Takeichi, Kazuo Tachibana

LIF - Molecular and Chemical Life Science

The University of Tokyo

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

A new strategy for the construction of O-linked oxepane ring system is described. The present method involves regioselective acetal cleavage by i- Bu₂AlSePh and intramolecular radical cyclization by use of β- alkoxyacrylate.

Original language	English
Pages (from-to)	2783-2786
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	18
DOIs	https://doi.org/10.1016/S0040-4039(98)00338-4
Publication status	Published - 1998 Apr 30

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10.1016/S0040-4039(98)00338-4

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title = "Convergent and stereoselective method for synthesis of O-linked oxepane ring system by intramolecular radical cyclization",

abstract = "A new strategy for the construction of O-linked oxepane ring system is described. The present method involves regioselective acetal cleavage by i- Bu2AlSePh and intramolecular radical cyclization by use of β- alkoxyacrylate.",

author = "Makoto Sasaki and Masayuki Inoue and Tetsuji Noguchi and Atsuo Takeichi and Kazuo Tachibana",

year = "1998",

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T1 - Convergent and stereoselective method for synthesis of O-linked oxepane ring system by intramolecular radical cyclization

AU - Sasaki, Makoto

AU - Inoue, Masayuki

AU - Noguchi, Tetsuji

AU - Takeichi, Atsuo

AU - Tachibana, Kazuo

PY - 1998/4/30

Y1 - 1998/4/30

N2 - A new strategy for the construction of O-linked oxepane ring system is described. The present method involves regioselective acetal cleavage by i- Bu2AlSePh and intramolecular radical cyclization by use of β- alkoxyacrylate.

AB - A new strategy for the construction of O-linked oxepane ring system is described. The present method involves regioselective acetal cleavage by i- Bu2AlSePh and intramolecular radical cyclization by use of β- alkoxyacrylate.

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U2 - 10.1016/S0040-4039(98)00338-4

DO - 10.1016/S0040-4039(98)00338-4

M3 - Article

AN - SCOPUS:0032580462

SN - 0040-4039

VL - 39

SP - 2783

EP - 2786

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 18

ER -

Convergent and stereoselective method for synthesis of O-linked oxepane ring system by intramolecular radical cyclization

Abstract

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