Convergent synthesis of an HIJK ring model of ciguatoxin via Suzuki cross-coupling reaction

Makoto Sasaki; Katsuhiko Noguchi; Haruhiko Fuwa; Kazuo Tachibana

doi:10.1016/S0040-4039(99)02307-2

Convergent synthesis of an HIJK ring model of ciguatoxin via Suzuki cross-coupling reaction

Makoto Sasaki, Katsuhiko Noguchi, Haruhiko Fuwa, Kazuo Tachibana

LIF - Molecular and Chemical Life Science

The University of Tokyo

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

Convergent synthesis of HIJK ring model compound 1 of ciguatoxin is described. The present synthesis relied on a palladium-catalyzed Suzuki cross-coupling reaction between eight-membered ketene acetal phosphate 2 and seven-membered alkylborane 6. (C) 2000 Elsevier Science Ltd.

Original language	English
Pages (from-to)	1425-1428
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	9
DOIs	https://doi.org/10.1016/S0040-4039(99)02307-2
Publication status	Published - 2000 Feb 26

Keywords

Coupling reactions
Polyethers
Suzuki reactions
Toxins

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10.1016/S0040-4039(99)02307-2

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abstract = "Convergent synthesis of HIJK ring model compound 1 of ciguatoxin is described. The present synthesis relied on a palladium-catalyzed Suzuki cross-coupling reaction between eight-membered ketene acetal phosphate 2 and seven-membered alkylborane 6. (C) 2000 Elsevier Science Ltd.",

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AU - Sasaki, Makoto

AU - Noguchi, Katsuhiko

AU - Fuwa, Haruhiko

AU - Tachibana, Kazuo

PY - 2000/2/26

Y1 - 2000/2/26

N2 - Convergent synthesis of HIJK ring model compound 1 of ciguatoxin is described. The present synthesis relied on a palladium-catalyzed Suzuki cross-coupling reaction between eight-membered ketene acetal phosphate 2 and seven-membered alkylborane 6. (C) 2000 Elsevier Science Ltd.

AB - Convergent synthesis of HIJK ring model compound 1 of ciguatoxin is described. The present synthesis relied on a palladium-catalyzed Suzuki cross-coupling reaction between eight-membered ketene acetal phosphate 2 and seven-membered alkylborane 6. (C) 2000 Elsevier Science Ltd.

KW - Coupling reactions

KW - Polyethers

KW - Suzuki reactions

KW - Toxins

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U2 - 10.1016/S0040-4039(99)02307-2

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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ER -

Convergent synthesis of an HIJK ring model of ciguatoxin via Suzuki cross-coupling reaction

Abstract

Keywords

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