Coordination distortion induced water adsorption in hydrophobic flexible metal-organic frameworks

Yoshinobu Kamakura; Arata Hikawa; Hirofumi Yoshikawa; Wataru Kosaka; Hitoshi Miyasaka; Daisuke Tanaka

doi:10.1039/d0cc03772a

Coordination distortion induced water adsorption in hydrophobic flexible metal-organic frameworks

Yoshinobu Kamakura, Arata Hikawa, Hirofumi Yoshikawa, Wataru Kosaka, Hitoshi Miyasaka, Daisuke Tanaka

IMR - Materials Development Division

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Herein, we synthesized four isostructural flexible interdigitated hydrophobic metal-organic frameworks that differ only in their central metal ion. The water-adsorption properties are dependent on the metal species, which was revealed to be caused by coordination distortion around the metal ions.

Original language	English
Pages (from-to)	9106-9109
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	64
DOIs	https://doi.org/10.1039/d0cc03772a
Publication status	Published - 2020 Aug 18

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title = "Coordination distortion induced water adsorption in hydrophobic flexible metal-organic frameworks",

abstract = "Herein, we synthesized four isostructural flexible interdigitated hydrophobic metal-organic frameworks that differ only in their central metal ion. The water-adsorption properties are dependent on the metal species, which was revealed to be caused by coordination distortion around the metal ions.",

author = "Yoshinobu Kamakura and Arata Hikawa and Hirofumi Yoshikawa and Wataru Kosaka and Hitoshi Miyasaka and Daisuke Tanaka",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

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AU - Kamakura, Yoshinobu

AU - Hikawa, Arata

AU - Yoshikawa, Hirofumi

AU - Kosaka, Wataru

AU - Miyasaka, Hitoshi

AU - Tanaka, Daisuke

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2020/8/18

Y1 - 2020/8/18

N2 - Herein, we synthesized four isostructural flexible interdigitated hydrophobic metal-organic frameworks that differ only in their central metal ion. The water-adsorption properties are dependent on the metal species, which was revealed to be caused by coordination distortion around the metal ions.

AB - Herein, we synthesized four isostructural flexible interdigitated hydrophobic metal-organic frameworks that differ only in their central metal ion. The water-adsorption properties are dependent on the metal species, which was revealed to be caused by coordination distortion around the metal ions.

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U2 - 10.1039/d0cc03772a

DO - 10.1039/d0cc03772a

M3 - Article

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SN - 1359-7345

VL - 56

SP - 9106

EP - 9109

JO - Chemical Communications

JF - Chemical Communications

IS - 64

ER -

Coordination distortion induced water adsorption in hydrophobic flexible metal-organic frameworks

Abstract

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