Copper and silver complexes containing the S(SiME2S)22- ligand: Efficient entries into heterometallic sulfido clusters

Takashi Komuro; Tsukasa Matsuo; Hiroyuki Kawaguchi; Kazuyuki Tatsumi

doi:10.1002/anie.200390141

Copper and silver complexes containing the S(SiME₂S)₂^2- ligand: Efficient entries into heterometallic sulfido clusters

Takashi Komuro, Tsukasa Matsuo, Hiroyuki Kawaguchi, Kazuyuki Tatsumi

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Thermally stable silanethiolato complexes of copper (1) and silver can be prepared readily by using cyclotrisilathiane. Com plex 1 a reacts with titanium-chloride complexes under mild conditions to produce copper-titanium sulfido clusters.

Original language	English
Pages (from-to)	465-468
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	4
DOIs	https://doi.org/10.1002/anie.200390141
Publication status	Published - 2003 Jan 27
Externally published	Yes

Keywords

Cluster compounds
Copper
S ligands
Si ligands
Titanium

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200390141

Cite this

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title = "Copper and silver complexes containing the S(SiME2S)22- ligand: Efficient entries into heterometallic sulfido clusters",

abstract = "Thermally stable silanethiolato complexes of copper (1) and silver can be prepared readily by using cyclotrisilathiane. Com plex 1 a reacts with titanium-chloride complexes under mild conditions to produce copper-titanium sulfido clusters.",

keywords = "Cluster compounds, Copper, S ligands, Si ligands, Titanium",

author = "Takashi Komuro and Tsukasa Matsuo and Hiroyuki Kawaguchi and Kazuyuki Tatsumi",

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AU - Matsuo, Tsukasa

AU - Kawaguchi, Hiroyuki

AU - Tatsumi, Kazuyuki

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AB - Thermally stable silanethiolato complexes of copper (1) and silver can be prepared readily by using cyclotrisilathiane. Com plex 1 a reacts with titanium-chloride complexes under mild conditions to produce copper-titanium sulfido clusters.

KW - Cluster compounds

KW - Copper

KW - S ligands

KW - Si ligands

KW - Titanium

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