TY - JOUR

T1 - Correct interpretation of hund's rule and chemical bonding based on the virial theorem

AU - Hongo, Kenta

AU - Oyamada, Takayuki

AU - Maruyama, Youhei

AU - Kawazoe, Yoshiyuki

AU - Yasuhara, Hiroshi

PY - 2007/4

Y1 - 2007/4

N2 - We have investigated Hund' s spin-multiplicity rule for the second and third row atoms (C, N, O, Si, P, and S) and the methylene molecule (CH 2) by means of diffusion Monte Carlo method and complete active space self-consistent field method, respectively. It is found that Hund's rule is interpreted to be ascribed to a lowering in the electron-nucleus attractive Coulomb interaction energy which is realized at the cost of increasing the electron-electron repulsive Coulomb interaction energy as well as the kinetic energy. We have also studied correlation in the hydrogen molecule H2. Correlation in H2 gives an increase of the electron density distribution n(r) in the left and right anti-binding regions, a reduction of n(r) in the binding region, and an increase in the equilibrium internuclear separation. The importance of the virial theorem is stressed in the evaluation of correlation effects on both Hund's rule and chemical bonding in H 2.

AB - We have investigated Hund' s spin-multiplicity rule for the second and third row atoms (C, N, O, Si, P, and S) and the methylene molecule (CH 2) by means of diffusion Monte Carlo method and complete active space self-consistent field method, respectively. It is found that Hund's rule is interpreted to be ascribed to a lowering in the electron-nucleus attractive Coulomb interaction energy which is realized at the cost of increasing the electron-electron repulsive Coulomb interaction energy as well as the kinetic energy. We have also studied correlation in the hydrogen molecule H2. Correlation in H2 gives an increase of the electron density distribution n(r) in the left and right anti-binding regions, a reduction of n(r) in the binding region, and an increase in the equilibrium internuclear separation. The importance of the virial theorem is stressed in the evaluation of correlation effects on both Hund's rule and chemical bonding in H 2.

KW - Chemical bonding

KW - Electron correlation

KW - Hund's rule

KW - Virial theorem

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U2 - 10.2320/matertrans.48.662

DO - 10.2320/matertrans.48.662

M3 - Article

AN - SCOPUS:34249786545

SN - 1345-9678

VL - 48

SP - 662

EP - 665

JO - Materials Transactions

JF - Materials Transactions

IS - 4

ER -