Crystal and magnetic structures of Y2CrS4

Keitaro Tezuka; Yue Jin Shan; Hideo Imoto; Kenji Ohoyama

doi:10.1016/j.jpcs.2007.08.016

Crystal and magnetic structures of Y₂CrS₄

Keitaro Tezuka, Yue Jin Shan, Hideo Imoto, Kenji Ohoyama

Institute for Materials Research (IMR)

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Chromium(II) sulfide, Y₂CrS₄, prepared by a solid-state reaction of Y₂S₃ and CrS, showed an antiferromagnetic transition at 65 K. The neutron diffraction patterns at 10 and 90 K were both well refined with the space group Pca2₁. At 90 K, cell parameters were a=12.5518(13) Å, b=7.5245(8) Å, and c=12.4918(13) Å. At 10 K, magnetic peaks were observed, which could be indexed on the same unit cell. Magnetic moments of chromium ions were parallel to the b-axis and antiferromagnetically ordered in each set of the 4a sites.

Original language	English
Pages (from-to)	2133-2137
Number of pages	5
Journal	Journal of Physics and Chemistry of Solids
Volume	68
Issue number	11
DOIs	https://doi.org/10.1016/j.jpcs.2007.08.016
Publication status	Published - 2007 Nov

Keywords

A. Chalcogenides
C. Neutron scattering
D. Crystal structure
D. Magnetic properties
D. Magnetic structure

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1016/j.jpcs.2007.08.016

Cite this

@article{c8c467790b28423db35bad4f02b7374e,

title = "Crystal and magnetic structures of Y2CrS4",

abstract = "Chromium(II) sulfide, Y2CrS4, prepared by a solid-state reaction of Y2S3 and CrS, showed an antiferromagnetic transition at 65 K. The neutron diffraction patterns at 10 and 90 K were both well refined with the space group Pca21. At 90 K, cell parameters were a=12.5518(13) {\AA}, b=7.5245(8) {\AA}, and c=12.4918(13) {\AA}. At 10 K, magnetic peaks were observed, which could be indexed on the same unit cell. Magnetic moments of chromium ions were parallel to the b-axis and antiferromagnetically ordered in each set of the 4a sites.",

keywords = "A. Chalcogenides, C. Neutron scattering, D. Crystal structure, D. Magnetic properties, D. Magnetic structure",

author = "Keitaro Tezuka and Shan, {Yue Jin} and Hideo Imoto and Kenji Ohoyama",

year = "2007",

month = nov,

doi = "10.1016/j.jpcs.2007.08.016",

language = "English",

volume = "68",

pages = "2133--2137",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier Limited",

number = "11",

}

TY - JOUR

T1 - Crystal and magnetic structures of Y2CrS4

AU - Tezuka, Keitaro

AU - Shan, Yue Jin

AU - Imoto, Hideo

AU - Ohoyama, Kenji

PY - 2007/11

Y1 - 2007/11

N2 - Chromium(II) sulfide, Y2CrS4, prepared by a solid-state reaction of Y2S3 and CrS, showed an antiferromagnetic transition at 65 K. The neutron diffraction patterns at 10 and 90 K were both well refined with the space group Pca21. At 90 K, cell parameters were a=12.5518(13) Å, b=7.5245(8) Å, and c=12.4918(13) Å. At 10 K, magnetic peaks were observed, which could be indexed on the same unit cell. Magnetic moments of chromium ions were parallel to the b-axis and antiferromagnetically ordered in each set of the 4a sites.

AB - Chromium(II) sulfide, Y2CrS4, prepared by a solid-state reaction of Y2S3 and CrS, showed an antiferromagnetic transition at 65 K. The neutron diffraction patterns at 10 and 90 K were both well refined with the space group Pca21. At 90 K, cell parameters were a=12.5518(13) Å, b=7.5245(8) Å, and c=12.4918(13) Å. At 10 K, magnetic peaks were observed, which could be indexed on the same unit cell. Magnetic moments of chromium ions were parallel to the b-axis and antiferromagnetically ordered in each set of the 4a sites.

KW - A. Chalcogenides

KW - C. Neutron scattering

KW - D. Crystal structure

KW - D. Magnetic properties

KW - D. Magnetic structure

UR - http://www.scopus.com/inward/record.url?scp=35748970746&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=35748970746&partnerID=8YFLogxK

U2 - 10.1016/j.jpcs.2007.08.016

DO - 10.1016/j.jpcs.2007.08.016

M3 - Article

AN - SCOPUS:35748970746

SN - 0022-3697

VL - 68

SP - 2133

EP - 2137

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

IS - 11

ER -