Crystal structure and magnetic properties of a dinuclear high-spin iron(III) complex with face-to-face bis(salen)-type ligands

Ryuta Ishikawa; Brian K. Breedlove; Masahiro Yamashita

doi:10.1002/ejic.201200914

Crystal structure and magnetic properties of a dinuclear high-spin iron(III) complex with face-to-face bis(salen)-type ligands

Ryuta Ishikawa, Brian K. Breedlove, Masahiro Yamashita

SCI - Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Synthesis and crystal structure of the dinuclear complex threo-[Fe ^III ₂(saltab)(Him)₄](ClO₂) ₂·2MeOH (1) {H₄saltab = (2R,3S)-1,2,3,4- tetrakis(salicylideneamino)butane, a bis-(salen)-type Schiff base ligand, and Him = imidazole} are reported. The magnetic behavior of 1 showed that it was in a high-spin state over the whole temperature region.

Original language	English
Pages (from-to)	716-719
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	5-6
DOIs	https://doi.org/10.1002/ejic.201200914
Publication status	Published - 2013 Feb

Keywords

Crystal engineering
Iron
Magnetic properties
Schiff bases
Solid-state structures

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10.1002/ejic.201200914

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title = "Crystal structure and magnetic properties of a dinuclear high-spin iron(III) complex with face-to-face bis(salen)-type ligands",

abstract = "Synthesis and crystal structure of the dinuclear complex threo-[Fe III 2(saltab)(Him)4](ClO2) 2·2MeOH (1) {H4saltab = (2R,3S)-1,2,3,4- tetrakis(salicylideneamino)butane, a bis-(salen)-type Schiff base ligand, and Him = imidazole} are reported. The magnetic behavior of 1 showed that it was in a high-spin state over the whole temperature region.",

keywords = "Crystal engineering, Iron, Magnetic properties, Schiff bases, Solid-state structures",

author = "Ryuta Ishikawa and Breedlove, {Brian K.} and Masahiro Yamashita",

year = "2013",

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doi = "10.1002/ejic.201200914",

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pages = "716--719",

journal = "European Journal of Inorganic Chemistry",

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T1 - Crystal structure and magnetic properties of a dinuclear high-spin iron(III) complex with face-to-face bis(salen)-type ligands

AU - Ishikawa, Ryuta

AU - Breedlove, Brian K.

AU - Yamashita, Masahiro

PY - 2013/2

Y1 - 2013/2

N2 - Synthesis and crystal structure of the dinuclear complex threo-[Fe III 2(saltab)(Him)4](ClO2) 2·2MeOH (1) {H4saltab = (2R,3S)-1,2,3,4- tetrakis(salicylideneamino)butane, a bis-(salen)-type Schiff base ligand, and Him = imidazole} are reported. The magnetic behavior of 1 showed that it was in a high-spin state over the whole temperature region.

AB - Synthesis and crystal structure of the dinuclear complex threo-[Fe III 2(saltab)(Him)4](ClO2) 2·2MeOH (1) {H4saltab = (2R,3S)-1,2,3,4- tetrakis(salicylideneamino)butane, a bis-(salen)-type Schiff base ligand, and Him = imidazole} are reported. The magnetic behavior of 1 showed that it was in a high-spin state over the whole temperature region.

KW - Crystal engineering

KW - Iron

KW - Magnetic properties

KW - Schiff bases

KW - Solid-state structures

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DO - 10.1002/ejic.201200914

M3 - Article

AN - SCOPUS:84875706760

SN - 1434-1948

SP - 716

EP - 719

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 5-6

ER -

Crystal structure and magnetic properties of a dinuclear high-spin iron(III) complex with face-to-face bis(salen)-type ligands

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Keywords

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