Crystal structure of a supramolecular cation salt (adamantylammonium +)2(benzo[18]crown-6)2[Pd(dmit) 2]2-(acetone)2

Kazuya Kubo; Yin Nan Yan; Shin Ichiro Noro; Tomoyuki Akutagawa; Takayoshi Nakamura

doi:10.1016/j.ica.2013.02.018

Crystal structure of a supramolecular cation salt (adamantylammonium ⁺)₂(benzo[18]crown-6)₂[Pd(dmit) ₂]^2-(acetone)₂

Kazuya Kubo, Yin Nan Yan, Shin Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura

IMRAM - Materials-Measurement Hybrid Research Center

Hokkaido University

Research output: Contribution to journal › Article › peer-review

Abstract

Single crystal of supramolecuar cation salt (adamantylammonium ⁺)₂(benzo[18]crown-6)₂[Pd(dmit) ₂]^2-(- acetone)₂ were synthesized by an electrochemical crystallization. In the crystal, two supramolecular cations and two acetones and one [Pd(dmit)₂]^2- dianion were crystallographically asymmetric. Molecular rotation of adamantyl groups was suggested from anisotropic thermal factors in the X-ray analysis at 173 K.

Original language	English
Pages (from-to)	206-209
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	404
DOIs	https://doi.org/10.1016/j.ica.2013.02.018
Publication status	Published - 2013

Keywords

Crystal structure
Electrochemical crystallization
Molecular motion
Pd-dithiolene complex
Supramolecular rotator

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10.1016/j.ica.2013.02.018

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title = "Crystal structure of a supramolecular cation salt (adamantylammonium +)2(benzo[18]crown-6)2[Pd(dmit) 2]2-(acetone)2",

abstract = "Single crystal of supramolecuar cation salt (adamantylammonium +)2(benzo[18]crown-6)2[Pd(dmit) 2]2-(- acetone)2 were synthesized by an electrochemical crystallization. In the crystal, two supramolecular cations and two acetones and one [Pd(dmit)2]2- dianion were crystallographically asymmetric. Molecular rotation of adamantyl groups was suggested from anisotropic thermal factors in the X-ray analysis at 173 K.",

keywords = "Crystal structure, Electrochemical crystallization, Molecular motion, Pd-dithiolene complex, Supramolecular rotator",

author = "Kazuya Kubo and Yan, {Yin Nan} and Noro, {Shin Ichiro} and Tomoyuki Akutagawa and Takayoshi Nakamura",

note = "Funding Information: This work was partly supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology . ",

year = "2013",

doi = "10.1016/j.ica.2013.02.018",

language = "English",

volume = "404",

pages = "206--209",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

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TY - JOUR

T1 - Crystal structure of a supramolecular cation salt (adamantylammonium +)2(benzo[18]crown-6)2[Pd(dmit) 2]2-(acetone)2

AU - Kubo, Kazuya

AU - Yan, Yin Nan

AU - Noro, Shin Ichiro

AU - Akutagawa, Tomoyuki

AU - Nakamura, Takayoshi

N1 - Funding Information: This work was partly supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology .

PY - 2013

Y1 - 2013

N2 - Single crystal of supramolecuar cation salt (adamantylammonium +)2(benzo[18]crown-6)2[Pd(dmit) 2]2-(- acetone)2 were synthesized by an electrochemical crystallization. In the crystal, two supramolecular cations and two acetones and one [Pd(dmit)2]2- dianion were crystallographically asymmetric. Molecular rotation of adamantyl groups was suggested from anisotropic thermal factors in the X-ray analysis at 173 K.

AB - Single crystal of supramolecuar cation salt (adamantylammonium +)2(benzo[18]crown-6)2[Pd(dmit) 2]2-(- acetone)2 were synthesized by an electrochemical crystallization. In the crystal, two supramolecular cations and two acetones and one [Pd(dmit)2]2- dianion were crystallographically asymmetric. Molecular rotation of adamantyl groups was suggested from anisotropic thermal factors in the X-ray analysis at 173 K.

KW - Crystal structure

KW - Electrochemical crystallization

KW - Molecular motion

KW - Pd-dithiolene complex

KW - Supramolecular rotator

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U2 - 10.1016/j.ica.2013.02.018

DO - 10.1016/j.ica.2013.02.018

M3 - Article

AN - SCOPUS:84879412223

SN - 0020-1693

VL - 404

SP - 206

EP - 209

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Crystal structure of a supramolecular cation salt (adamantylammonium ⁺)₂(benzo[18]crown-6)₂[Pd(dmit) ₂]^2-(acetone)₂

Abstract

Keywords

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