Crystal structure of TiBi2

Kei Watanabe; Hisanori Yamane

doi:10.1107/S2056989016012391

Crystal structure of TiBi₂

Kei Watanabe, Hisanori Yamane

IMRAM - Division of Inorganic Material Research

Tohoku University

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Black granular single crystals of monotitanium dibismuth, TiBi2, were synthesized by slow cooling of a mixture of Bi and Ti from 693-K. The title compound is isostructural with CuMg2 (orthorhombic Fddd symmetry). Ti atoms are located in square antiprisms of Bi atoms. The network of one type of Bi atom spirals along the a-axis direction while honeycomb layers of the other type of Bi atom spreading in the ab plane interlace one another.

Original language	English
Pages (from-to)	1254-1256
Number of pages	3
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	72
DOIs	https://doi.org/10.1107/S2056989016012391
Publication status	Published - 2016

Keywords

bismuth
crystal structure
CuMg structure type
titanium

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10.1107/S2056989016012391

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abstract = "Black granular single crystals of monotitanium dibismuth, TiBi2, were synthesized by slow cooling of a mixture of Bi and Ti from 693-K. The title compound is isostructural with CuMg2 (orthorhombic Fddd symmetry). Ti atoms are located in square antiprisms of Bi atoms. The network of one type of Bi atom spirals along the a-axis direction while honeycomb layers of the other type of Bi atom spreading in the ab plane interlace one another.",

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author = "Kei Watanabe and Hisanori Yamane",

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doi = "10.1107/S2056989016012391",

language = "English",

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pages = "1254--1256",

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AU - Watanabe, Kei

AU - Yamane, Hisanori

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PY - 2016

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N2 - Black granular single crystals of monotitanium dibismuth, TiBi2, were synthesized by slow cooling of a mixture of Bi and Ti from 693-K. The title compound is isostructural with CuMg2 (orthorhombic Fddd symmetry). Ti atoms are located in square antiprisms of Bi atoms. The network of one type of Bi atom spirals along the a-axis direction while honeycomb layers of the other type of Bi atom spreading in the ab plane interlace one another.

AB - Black granular single crystals of monotitanium dibismuth, TiBi2, were synthesized by slow cooling of a mixture of Bi and Ti from 693-K. The title compound is isostructural with CuMg2 (orthorhombic Fddd symmetry). Ti atoms are located in square antiprisms of Bi atoms. The network of one type of Bi atom spirals along the a-axis direction while honeycomb layers of the other type of Bi atom spreading in the ab plane interlace one another.

KW - bismuth

KW - crystal structure

KW - CuMg structure type

KW - titanium

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JO - Acta Crystallographica Section E: Crystallographic Communications

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ER -

Crystal structure of TiBi₂

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Keywords

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