Crystal structures and magnetic properties of [Ni(dmit)2] - salts including (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) supramolecular cations

S. Nishihara; X. M. Ren; T. Akutagawa; T. Nakamura

doi:10.1016/j.poly.2005.03.163

Crystal structures and magnetic properties of [Ni(dmit)₂] ^- salts including (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) supramolecular cations

S. Nishihara, X. M. Ren, T. Akutagawa, T. Nakamura

IMRAM - Materials-Measurement Hybrid Research Center

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

New supramolecular cation structures of (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) were introduced as counter cations to [Ni(dmit)₂]^- salts, which bear an S = 1/2 spin, to form magnetic crystals. From the crystal structures and temperature dependent magnetic susceptibilities, both salts had isomorphous structure of one-dimensional arrangements of [Ni(dmit)₂]^- π-dimer along the b-axis. The magnetic ground state of these salts was spin singlet with the intradimer magnetic exchange energy of around -150 K.

Original language	English
Pages (from-to)	2844-2848
Number of pages	5
Journal	Polyhedron
Volume	24
Issue number	16-17
DOIs	https://doi.org/10.1016/j.poly.2005.03.163
Publication status	Published - 2005 Nov 17

Keywords

Crown ether
Crystal structure
Magnetic susceptibility
Molecular magnetism
Supramolecular cation
[Ni(dmit)]

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10.1016/j.poly.2005.03.163

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title = "Crystal structures and magnetic properties of [Ni(dmit)2] - salts including (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) supramolecular cations",

abstract = "New supramolecular cation structures of (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) were introduced as counter cations to [Ni(dmit)2]- salts, which bear an S = 1/2 spin, to form magnetic crystals. From the crystal structures and temperature dependent magnetic susceptibilities, both salts had isomorphous structure of one-dimensional arrangements of [Ni(dmit)2]- π-dimer along the b-axis. The magnetic ground state of these salts was spin singlet with the intradimer magnetic exchange energy of around -150 K.",

keywords = "Crown ether, Crystal structure, Magnetic susceptibility, Molecular magnetism, Supramolecular cation, [Ni(dmit)]",

author = "S. Nishihara and Ren, {X. M.} and T. Akutagawa and T. Nakamura",

note = "Funding Information: The authors thank Dr. K. Ichimura and Professor K. Nomura for the use of SQUID magnetometer. S.N. thanks for supporting from the research fellowship of the Japan Society for the Promotion of Science (JSPS) for young scientists. X.M.R gives thanks to JSPS for financial support.",

year = "2005",

month = nov,

day = "17",

doi = "10.1016/j.poly.2005.03.163",

language = "English",

volume = "24",

pages = "2844--2848",

journal = "Polyhedron",

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T1 - Crystal structures and magnetic properties of [Ni(dmit)2] - salts including (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) supramolecular cations

AU - Nishihara, S.

AU - Ren, X. M.

AU - Akutagawa, T.

AU - Nakamura, T.

N1 - Funding Information: The authors thank Dr. K. Ichimura and Professor K. Nomura for the use of SQUID magnetometer. S.N. thanks for supporting from the research fellowship of the Japan Society for the Promotion of Science (JSPS) for young scientists. X.M.R gives thanks to JSPS for financial support.

PY - 2005/11/17

Y1 - 2005/11/17

N2 - New supramolecular cation structures of (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) were introduced as counter cations to [Ni(dmit)2]- salts, which bear an S = 1/2 spin, to form magnetic crystals. From the crystal structures and temperature dependent magnetic susceptibilities, both salts had isomorphous structure of one-dimensional arrangements of [Ni(dmit)2]- π-dimer along the b-axis. The magnetic ground state of these salts was spin singlet with the intradimer magnetic exchange energy of around -150 K.

AB - New supramolecular cation structures of (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) were introduced as counter cations to [Ni(dmit)2]- salts, which bear an S = 1/2 spin, to form magnetic crystals. From the crystal structures and temperature dependent magnetic susceptibilities, both salts had isomorphous structure of one-dimensional arrangements of [Ni(dmit)2]- π-dimer along the b-axis. The magnetic ground state of these salts was spin singlet with the intradimer magnetic exchange energy of around -150 K.

KW - Crown ether

KW - Crystal structure

KW - Magnetic susceptibility

KW - Molecular magnetism

KW - Supramolecular cation

KW - [Ni(dmit)]

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U2 - 10.1016/j.poly.2005.03.163

DO - 10.1016/j.poly.2005.03.163

M3 - Article

AN - SCOPUS:27644543649

SN - 0277-5387

VL - 24

SP - 2844

EP - 2848

JO - Polyhedron

JF - Polyhedron

IS - 16-17

ER -

Crystal structures and magnetic properties of [Ni(dmit)₂] ^- salts including (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) supramolecular cations

Abstract

Keywords

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