[Cu(dap) 2Cl] as an efficient visible-light-driven photoredox catalyst in carbon-carbon bond-forming reactions

Michael Pirtsch; Suva Paria; Taisuke Matsuno; Hiroyuki Isobe; Oliver Reiser

doi:10.1002/chem.201200967

[Cu(dap) ₂Cl] as an efficient visible-light-driven photoredox catalyst in carbon-carbon bond-forming reactions

Michael Pirtsch, Suva Paria, Taisuke Matsuno, Hiroyuki Isobe, Oliver Reiser

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

263 Citations (Scopus)

Abstract

Copper sees the light of day: [Cu(dap) ₂Cl] proved to be an excellent photoredox catalyst for atom-transfer radical addition reactions, as well as for allylation reactions (see scheme), providing an attractive alternative to commonly used iridium- and ruthenium-based catalysts.

Original language	English
Pages (from-to)	7336-7340
Number of pages	5
Journal	Chemistry - A European Journal
Volume	18
Issue number	24
DOIs	https://doi.org/10.1002/chem.201200967
Publication status	Published - 2012 Jun 11

Keywords

allylation
atom-transfer radical addition
copper
photochemistry
redox chemistry

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1002/chem.201200967

Cite this

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abstract = "Copper sees the light of day: [Cu(dap) 2Cl] proved to be an excellent photoredox catalyst for atom-transfer radical addition reactions, as well as for allylation reactions (see scheme), providing an attractive alternative to commonly used iridium- and ruthenium-based catalysts.",

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AU - Matsuno, Taisuke

AU - Isobe, Hiroyuki

AU - Reiser, Oliver

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N2 - Copper sees the light of day: [Cu(dap) 2Cl] proved to be an excellent photoredox catalyst for atom-transfer radical addition reactions, as well as for allylation reactions (see scheme), providing an attractive alternative to commonly used iridium- and ruthenium-based catalysts.

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KW - atom-transfer radical addition

KW - copper

KW - photochemistry

KW - redox chemistry

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