Deep Axial Inclusion of Two Aromatic Molecules by Dimethyl-β-Cyclodextrin and β-Cyclodextrin

Yayoi Kobayashi; Tomonori Hoshi; Satoshi Yamamoto; Mutsumi Kimura; Nagao Kobayashi

doi:10.1002/slct.201702089

Deep Axial Inclusion of Two Aromatic Molecules by Dimethyl-β-Cyclodextrin and β-Cyclodextrin

Yayoi Kobayashi, Tomonori Hoshi, Satoshi Yamamoto, Mutsumi Kimura, Nagao Kobayashi

HOSP - Clinical Research, Innovation and Education Center

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Electronic absorption, induced circular dichroism, and ¹H NMR spectroscopies, together with molecular orbital calculations, have indicated the attainment of a deep axial inclusion of two aromatic molecules by β-cyclodextrin and dimethyl-β-cyclodextrin, by selecting quinhydrone (1:1 compound consisting of benzoquinone and hydroquinone) as a guest molecule.

Original language	English
Pages (from-to)	9847-9850
Number of pages	4
Journal	ChemistrySelect
Volume	2
Issue number	30
DOIs	https://doi.org/10.1002/slct.201702089
Publication status	Published - 2017 Oct 23

Keywords

Circular Dichroism
Cyclodextrins
Host-Guest Systems
Inclusion Compounds
Quinhydrone

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10.1002/slct.201702089

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title = "Deep Axial Inclusion of Two Aromatic Molecules by Dimethyl-β-Cyclodextrin and β-Cyclodextrin",

abstract = "Electronic absorption, induced circular dichroism, and 1H NMR spectroscopies, together with molecular orbital calculations, have indicated the attainment of a deep axial inclusion of two aromatic molecules by β-cyclodextrin and dimethyl-β-cyclodextrin, by selecting quinhydrone (1:1 compound consisting of benzoquinone and hydroquinone) as a guest molecule.",

keywords = "Circular Dichroism, Cyclodextrins, Host-Guest Systems, Inclusion Compounds, Quinhydrone",

author = "Yayoi Kobayashi and Tomonori Hoshi and Satoshi Yamamoto and Mutsumi Kimura and Nagao Kobayashi",

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AU - Kobayashi, Yayoi

AU - Hoshi, Tomonori

AU - Yamamoto, Satoshi

AU - Kimura, Mutsumi

AU - Kobayashi, Nagao

PY - 2017/10/23

Y1 - 2017/10/23

N2 - Electronic absorption, induced circular dichroism, and 1H NMR spectroscopies, together with molecular orbital calculations, have indicated the attainment of a deep axial inclusion of two aromatic molecules by β-cyclodextrin and dimethyl-β-cyclodextrin, by selecting quinhydrone (1:1 compound consisting of benzoquinone and hydroquinone) as a guest molecule.

AB - Electronic absorption, induced circular dichroism, and 1H NMR spectroscopies, together with molecular orbital calculations, have indicated the attainment of a deep axial inclusion of two aromatic molecules by β-cyclodextrin and dimethyl-β-cyclodextrin, by selecting quinhydrone (1:1 compound consisting of benzoquinone and hydroquinone) as a guest molecule.

KW - Circular Dichroism

KW - Cyclodextrins

KW - Host-Guest Systems

KW - Inclusion Compounds

KW - Quinhydrone

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JO - ChemistrySelect

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ER -

Deep Axial Inclusion of Two Aromatic Molecules by Dimethyl-β-Cyclodextrin and β-Cyclodextrin

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Keywords

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