Dehydrogenative coupling of monohydrosilanes mediated by (2-phosphinoethyl)silylrhodium(I) complex

Masaaki Okazaki; Shin Ohshitanai; Hiromi Tobita; Hiroshi Ogino

doi:10.1246/cl.2001.952

Dehydrogenative coupling of monohydrosilanes mediated by (2-phosphinoethyl)silylrhodium(I) complex

Masaaki Okazaki, Shin Ohshitanai, Hiromi Tobita, Hiroshi Ogino

IEHE - Institute for Excellence in Higher Education (organization affiliation only)

Tohoku University

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Treatment of HSiMe₂Ph with a square-planar rhodium(I) complex Rh[(κ²-Si,P)-Me₂SiCH₂CH ₂PPh₂](PMe₃)₂ gave rise to selective dehydrogenative coupling of hydrosilanes to afford (SiMe₂Ph)₂ and RhH₂[(κ²-Si,P)-Me₂SiCH₂CH ₂PPh₂](PMe₃)₂.

Original language	English
Pages (from-to)	952-953
Number of pages	2
Journal	Chemistry Letters
Issue number	10
DOIs	https://doi.org/10.1246/cl.2001.952
Publication status	Published - 2001

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10.1246/cl.2001.952

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title = "Dehydrogenative coupling of monohydrosilanes mediated by (2-phosphinoethyl)silylrhodium(I) complex",

abstract = "Treatment of HSiMe2Ph with a square-planar rhodium(I) complex Rh[(κ2-Si,P)-Me2SiCH2CH 2PPh2](PMe3)2 gave rise to selective dehydrogenative coupling of hydrosilanes to afford (SiMe2Ph)2 and RhH2[(κ2-Si,P)-Me2SiCH2CH 2PPh2](PMe3)2.",

author = "Masaaki Okazaki and Shin Ohshitanai and Hiromi Tobita and Hiroshi Ogino",

year = "2001",

doi = "10.1246/cl.2001.952",

language = "English",

pages = "952--953",

journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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T1 - Dehydrogenative coupling of monohydrosilanes mediated by (2-phosphinoethyl)silylrhodium(I) complex

AU - Okazaki, Masaaki

AU - Ohshitanai, Shin

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 2001

Y1 - 2001

N2 - Treatment of HSiMe2Ph with a square-planar rhodium(I) complex Rh[(κ2-Si,P)-Me2SiCH2CH 2PPh2](PMe3)2 gave rise to selective dehydrogenative coupling of hydrosilanes to afford (SiMe2Ph)2 and RhH2[(κ2-Si,P)-Me2SiCH2CH 2PPh2](PMe3)2.

AB - Treatment of HSiMe2Ph with a square-planar rhodium(I) complex Rh[(κ2-Si,P)-Me2SiCH2CH 2PPh2](PMe3)2 gave rise to selective dehydrogenative coupling of hydrosilanes to afford (SiMe2Ph)2 and RhH2[(κ2-Si,P)-Me2SiCH2CH 2PPh2](PMe3)2.

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DO - 10.1246/cl.2001.952

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

ER -

Dehydrogenative coupling of monohydrosilanes mediated by (2-phosphinoethyl)silylrhodium(I) complex

Abstract

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