Desulfurization with hydrogen production by BS process

Nobuaki Sato; Hiroaki Kanazawa; Etsuro Shibata; Takashi Nakamura; Shin Tomisaki; Hitoshi Kuroda; Hirosi Shiraishi

Desulfurization with hydrogen production by BS process

Nobuaki Sato, Hiroaki Kanazawa, Etsuro Shibata, Takashi Nakamura, Shin Tomisaki, Hitoshi Kuroda, Hirosi Shiraishi

IMRAM - Center for Mineral Processing and Metallurgy (CMPM)

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

For decontamination of SO₂ containing waste gases from industries such as ferrous and non-ferrous metal companies, desulfurization with hydrogen production by the reaction of Br₂ and SO₂ was proposed as bromine-sulfur (BS) process. In this process, SO₂ is fixed as H₂SO₄ in the presence of Br₂ and H₂O forming H₂SO₄ and HBr. Then hydrogen is produced by the decomposition of HBr and Br₂ as byproduct is recycled. The reaction of Br₂, SO₂ and H₂O was found not to occur in liquid phase but to occur in vapor one. The production ratios of H₂SO₄ and HBr showed a maximum at temperatures around 60°C. The highest production ratio was obtained at 70°C with a mixing ratio of Br₂:SO₂:H₂O=1:1:10. The experimental results were discussed with thermodynamic consideration.

Original language	English
Title of host publication	Sohn International Symposium
Subtitle of host publication	Advanced Processing of Metals and Materials - Proceedings of the International Symposium
Pages	487-492
Number of pages	6
Publication status	Published - 2006
Event	2006 TMS Fall Extraction and Processing Division: Sohn International Symposium - San Diego, CA, United States Duration: 2006 Aug 27 → 2006 Aug 31

Publication series

Name	2006 TMS Fall Extraction and Processing Division: Sohn International Symposium
Volume	1

Conference

Conference	2006 TMS Fall Extraction and Processing Division: Sohn International Symposium
Country/Territory	United States
City	San Diego, CA
Period	06/8/27 → 06/8/31

Keywords

Bromine
Hydrogen production
Sulfur dioxide
Sulfuric acid

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Cite this

Sato, N., Kanazawa, H., Shibata, E., Nakamura, T., Tomisaki, S., Kuroda, H., & Shiraishi, H. (2006). Desulfurization with hydrogen production by BS process. In Sohn International Symposium: Advanced Processing of Metals and Materials - Proceedings of the International Symposium (pp. 487-492). (2006 TMS Fall Extraction and Processing Division: Sohn International Symposium; Vol. 1).

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title = "Desulfurization with hydrogen production by BS process",

abstract = "For decontamination of SO2 containing waste gases from industries such as ferrous and non-ferrous metal companies, desulfurization with hydrogen production by the reaction of Br2 and SO2 was proposed as bromine-sulfur (BS) process. In this process, SO2 is fixed as H2SO4 in the presence of Br2 and H2O forming H2SO4 and HBr. Then hydrogen is produced by the decomposition of HBr and Br2 as byproduct is recycled. The reaction of Br2, SO2 and H2O was found not to occur in liquid phase but to occur in vapor one. The production ratios of H2SO4 and HBr showed a maximum at temperatures around 60°C. The highest production ratio was obtained at 70°C with a mixing ratio of Br2:SO2:H2O=1:1:10. The experimental results were discussed with thermodynamic consideration.",

keywords = "Bromine, Hydrogen production, Sulfur dioxide, Sulfuric acid",

author = "Nobuaki Sato and Hiroaki Kanazawa and Etsuro Shibata and Takashi Nakamura and Shin Tomisaki and Hitoshi Kuroda and Hirosi Shiraishi",

year = "2006",

language = "English",

isbn = "0873396332",

series = "2006 TMS Fall Extraction and Processing Division: Sohn International Symposium",

pages = "487--492",

booktitle = "Sohn International Symposium",

note = "2006 TMS Fall Extraction and Processing Division: Sohn International Symposium ; Conference date: 27-08-2006 Through 31-08-2006",

}

Sato, N, Kanazawa, H, Shibata, E, Nakamura, T, Tomisaki, S, Kuroda, H & Shiraishi, H 2006, Desulfurization with hydrogen production by BS process. in Sohn International Symposium: Advanced Processing of Metals and Materials - Proceedings of the International Symposium. 2006 TMS Fall Extraction and Processing Division: Sohn International Symposium, vol. 1, pp. 487-492, 2006 TMS Fall Extraction and Processing Division: Sohn International Symposium, San Diego, CA, United States, 06/8/27.

Desulfurization with hydrogen production by BS process. / Sato, Nobuaki; Kanazawa, Hiroaki; Shibata, Etsuro et al.
Sohn International Symposium: Advanced Processing of Metals and Materials - Proceedings of the International Symposium. 2006. p. 487-492 (2006 TMS Fall Extraction and Processing Division: Sohn International Symposium; Vol. 1).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Desulfurization with hydrogen production by BS process

AU - Sato, Nobuaki

AU - Kanazawa, Hiroaki

AU - Shibata, Etsuro

AU - Nakamura, Takashi

AU - Tomisaki, Shin

AU - Kuroda, Hitoshi

AU - Shiraishi, Hirosi

PY - 2006

Y1 - 2006

N2 - For decontamination of SO2 containing waste gases from industries such as ferrous and non-ferrous metal companies, desulfurization with hydrogen production by the reaction of Br2 and SO2 was proposed as bromine-sulfur (BS) process. In this process, SO2 is fixed as H2SO4 in the presence of Br2 and H2O forming H2SO4 and HBr. Then hydrogen is produced by the decomposition of HBr and Br2 as byproduct is recycled. The reaction of Br2, SO2 and H2O was found not to occur in liquid phase but to occur in vapor one. The production ratios of H2SO4 and HBr showed a maximum at temperatures around 60°C. The highest production ratio was obtained at 70°C with a mixing ratio of Br2:SO2:H2O=1:1:10. The experimental results were discussed with thermodynamic consideration.

AB - For decontamination of SO2 containing waste gases from industries such as ferrous and non-ferrous metal companies, desulfurization with hydrogen production by the reaction of Br2 and SO2 was proposed as bromine-sulfur (BS) process. In this process, SO2 is fixed as H2SO4 in the presence of Br2 and H2O forming H2SO4 and HBr. Then hydrogen is produced by the decomposition of HBr and Br2 as byproduct is recycled. The reaction of Br2, SO2 and H2O was found not to occur in liquid phase but to occur in vapor one. The production ratios of H2SO4 and HBr showed a maximum at temperatures around 60°C. The highest production ratio was obtained at 70°C with a mixing ratio of Br2:SO2:H2O=1:1:10. The experimental results were discussed with thermodynamic consideration.

KW - Bromine

KW - Hydrogen production

KW - Sulfur dioxide

KW - Sulfuric acid

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M3 - Conference contribution

AN - SCOPUS:33846072597

SN - 0873396332

SN - 9780873396332

T3 - 2006 TMS Fall Extraction and Processing Division: Sohn International Symposium

SP - 487

EP - 492

BT - Sohn International Symposium

T2 - 2006 TMS Fall Extraction and Processing Division: Sohn International Symposium

Y2 - 27 August 2006 through 31 August 2006

ER -

Desulfurization with hydrogen production by BS process

Abstract

Publication series

Conference

Keywords

UN SDGs

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