TY - JOUR

T1 - Determination of the crystal system and space group of (formula presented) by convergent-beam electron diffraction and x-ray diffraction using synchrotron radiation

AU - Hashimoto, Takuya

AU - Tsuda, Kenji

AU - Shiono, Junichiro

AU - Mizusaki, Junichiro

AU - Tanaka, Michiyoshi

PY - 2001

Y1 - 2001

N2 - The crystal system and space group of (formula presented) with a distorted perovskite structure were investigated by convergent-beam electron diffraction (CBED), selected area electron diffraction, and x-ray diffraction using synchrotron radiation. Since all the observed CBED patterns showed a symmetry of 1, and the (formula presented) dark-field disk of CBED patterns indicated the absence of an inversion center in (formula presented) the crystal symmetry of (formula presented) was concluded to be triclinic with a space group of (formula presented) (No. 1). The diffraction angles of the x-ray-diffraction peaks of (formula presented) obtained using synchrotron radiation, could apparently be explained by assuming a monoclinic symmetry. However, a larger full width at half maximum (FWHM) of the 440 peak, indexed assuming a monoclinic symmetry other than that of each peak of 008, (formula presented) 404, and 044 could not be explained. The large FWHM of the 440 peak could be attributed to an overlapping of the (formula presented) and 440 peaks of triclinic symmetry, showing agreement with the result of CBED.

AB - The crystal system and space group of (formula presented) with a distorted perovskite structure were investigated by convergent-beam electron diffraction (CBED), selected area electron diffraction, and x-ray diffraction using synchrotron radiation. Since all the observed CBED patterns showed a symmetry of 1, and the (formula presented) dark-field disk of CBED patterns indicated the absence of an inversion center in (formula presented) the crystal symmetry of (formula presented) was concluded to be triclinic with a space group of (formula presented) (No. 1). The diffraction angles of the x-ray-diffraction peaks of (formula presented) obtained using synchrotron radiation, could apparently be explained by assuming a monoclinic symmetry. However, a larger full width at half maximum (FWHM) of the 440 peak, indexed assuming a monoclinic symmetry other than that of each peak of 008, (formula presented) 404, and 044 could not be explained. The large FWHM of the 440 peak could be attributed to an overlapping of the (formula presented) and 440 peaks of triclinic symmetry, showing agreement with the result of CBED.

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U2 - 10.1103/PhysRevB.64.224114

DO - 10.1103/PhysRevB.64.224114

M3 - Article

AN - SCOPUS:84878609549

SN - 1098-0121

VL - 64

JO - Physical Review B - Condensed Matter and Materials Physics

JF - Physical Review B - Condensed Matter and Materials Physics

IS - 22

ER -