Deuterium Migration Mechanism in Chiral Thiolactam Formation by Neutron Diffraction Analysis

Takaaki Hosoya; Hidehiro Uekusa; Yuji Ohashi; Takashi Ohhara; Hiroyuki Kimura; Yukio Noda

doi:10.1246/cl.2003.742

Deuterium Migration Mechanism in Chiral Thiolactam Formation by Neutron Diffraction Analysis

Takaaki Hosoya, Hidehiro Uekusa, Yuji Ohashi, Takashi Ohhara, Hiroyuki Kimura, Yukio Noda

Division of Measurements

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The single-crystal neutron diffraction revealed that in the process of photo-induced β-thiolactam formation from N,N-dibenzyl-1- cyclohexenecarbothioamide a deuterium atom bonded to the benzyl carbon atom is transferred to the intramolecular cyclohexene carbon to occupy the equatorial position of the produced cyclohexyl ring.

Original language	English
Pages (from-to)	742-743
Number of pages	2
Journal	Chemistry Letters
Volume	32
Issue number	8
DOIs	https://doi.org/10.1246/cl.2003.742
Publication status	Published - 2003 Aug 5

ASJC Scopus subject areas

Chemistry(all)

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title = "Deuterium Migration Mechanism in Chiral Thiolactam Formation by Neutron Diffraction Analysis",

abstract = "The single-crystal neutron diffraction revealed that in the process of photo-induced β-thiolactam formation from N,N-dibenzyl-1- cyclohexenecarbothioamide a deuterium atom bonded to the benzyl carbon atom is transferred to the intramolecular cyclohexene carbon to occupy the equatorial position of the produced cyclohexyl ring.",

author = "Takaaki Hosoya and Hidehiro Uekusa and Yuji Ohashi and Takashi Ohhara and Hiroyuki Kimura and Yukio Noda",

year = "2003",

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T1 - Deuterium Migration Mechanism in Chiral Thiolactam Formation by Neutron Diffraction Analysis

AU - Hosoya, Takaaki

AU - Uekusa, Hidehiro

AU - Ohashi, Yuji

AU - Ohhara, Takashi

AU - Kimura, Hiroyuki

AU - Noda, Yukio

PY - 2003/8/5

Y1 - 2003/8/5

N2 - The single-crystal neutron diffraction revealed that in the process of photo-induced β-thiolactam formation from N,N-dibenzyl-1- cyclohexenecarbothioamide a deuterium atom bonded to the benzyl carbon atom is transferred to the intramolecular cyclohexene carbon to occupy the equatorial position of the produced cyclohexyl ring.

AB - The single-crystal neutron diffraction revealed that in the process of photo-induced β-thiolactam formation from N,N-dibenzyl-1- cyclohexenecarbothioamide a deuterium atom bonded to the benzyl carbon atom is transferred to the intramolecular cyclohexene carbon to occupy the equatorial position of the produced cyclohexyl ring.

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DO - 10.1246/cl.2003.742

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JO - Chemistry Letters

JF - Chemistry Letters

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ER -

Deuterium Migration Mechanism in Chiral Thiolactam Formation by Neutron Diffraction Analysis

Abstract

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