Development and application of 2.5 GPa–25 T high-pressure high-field electron spin resonance system using a cryogen-free superconducting magnet

We have developed a high-pressure electron spin resonance probe and successfully installed into the world's highest-field cryogen-free superconducting magnet having a maximum central field of 24.6 T. The high pressure of 2.5 GPa is achieved by the specially designed piston-cylinder pressure cell using THz-wave-transparent components. In the first application of this high-pressure high-field ESR system, we observed that the orthogonal dimer spin system SrCu₂(BO₃)₂ undergoes a quantum phase transition from the dimer singlet ground to the plaquette singlet ground states.