Development of a site-selective copper-ion-exchanging method for HZSM-5 by vapourization of a hexafluoroacetylacetonato-copper complex

Yasushige Kuroda; Kazunori Yagi; Yuzo Yoshikawa; Ryotaro Kumashiro; Mahiko Nagao

doi:10.1039/a706147a

Development of a site-selective copper-ion-exchanging method for HZSM-5 by vapourization of a hexafluoroacetylacetonato-copper complex

Yasushige Kuroda, Kazunori Yagi, Yuzo Yoshikawa, Ryotaro Kumashiro, Mahiko Nagao

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The deposition of copper ion into a single type of ion-exchange site in HZSM-5-type zeolite is successful using bis(1,1,1,5,5,5-hexafluoroacetylacetonato)copper(II) as a volatile complex, and the sample thus prepared gives a single IR absorption band at 2158 cm^-1 upon adsorption of CO, differing from a sample prepared by aqueous ion-exchange, which gives two bands at 2158 and 2151 cm^-1.

Original language	English
Pages (from-to)	2241-2242
Number of pages	2
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/a706147a
Publication status	Published - 1997 Jan 1

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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AU - Kuroda, Yasushige

AU - Yagi, Kazunori

AU - Yoshikawa, Yuzo

AU - Kumashiro, Ryotaro

AU - Nagao, Mahiko

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The deposition of copper ion into a single type of ion-exchange site in HZSM-5-type zeolite is successful using bis(1,1,1,5,5,5-hexafluoroacetylacetonato)copper(II) as a volatile complex, and the sample thus prepared gives a single IR absorption band at 2158 cm-1 upon adsorption of CO, differing from a sample prepared by aqueous ion-exchange, which gives two bands at 2158 and 2151 cm-1.

AB - The deposition of copper ion into a single type of ion-exchange site in HZSM-5-type zeolite is successful using bis(1,1,1,5,5,5-hexafluoroacetylacetonato)copper(II) as a volatile complex, and the sample thus prepared gives a single IR absorption band at 2158 cm-1 upon adsorption of CO, differing from a sample prepared by aqueous ion-exchange, which gives two bands at 2158 and 2151 cm-1.

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Development of a site-selective copper-ion-exchanging method for HZSM-5 by vapourization of a hexafluoroacetylacetonato-copper complex

Abstract

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