Development of single-component molecular metals based on extended-TTF dithiolate ligands

A. Kobayashi; W. Suzuki; E. Fujiwara; H. Tanaka; Y. Fujishiro; E. Nishibori; M. Takata; M. Sakata; Y. Okanao; H. Kobayashi

doi:10.1016/S0379-6779(02)00703-8

Development of single-component molecular metals based on extended-TTF dithiolate ligands

A. Kobayashi, W. Suzuki, E. Fujiwara, H. Tanaka, Y. Fujishiro, E. Nishibori, M. Takata, M. Sakata, Y. Okanao, H. Kobayashi

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The novel nickel complex with the extended-TTF dithiolate ligand [Ni(tmdt)₂] (tmdt²= trimethylenedithiotetrathiafulvalenedithiolate) is the first three-dimensional single-component molecular metal. Structures and physical properties of analogous single-component molecular conductors [Ni(dmdt)₂] (dmdt^2-=dimethyltetrathiafulvalenedithiolate), [Ni(codt)₂] (codt^2-=ethylenedioxytetrathiafulvalenedithiolate) and [Pd(C3-tdt)^2-] [(C3-tdt)^2-= dipropylthiotetrathiafulvalenedithiolate] were examined. The structure of [Au(tmdt)₂] was determined by synchrotron radiation powder diffraction experiments and the MEM/Rietveld analysis. The single-component paramagnetic molecule [Cu(dmdt)₂] was also studied to clarify the possibility of single-component magnetic molecular conductors.

Original language	English
Pages (from-to)	511-513
Number of pages	3
Journal	Synthetic Metals
Volume	135-136
DOIs	https://doi.org/10.1016/S0379-6779(02)00703-8
Publication status	Published - 2003 Apr 4
Externally published	Yes

Keywords

Diffraction and scattering
Electrocrystallization
Organic conductors based on radical cation and/or anion salts
X-ray emission

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/S0379-6779(02)00703-8

Cite this

@article{1322a6b5761b45aaa6976d0e68ecdfe7,

title = "Development of single-component molecular metals based on extended-TTF dithiolate ligands",

abstract = "The novel nickel complex with the extended-TTF dithiolate ligand [Ni(tmdt)2] (tmdt2= trimethylenedithiotetrathiafulvalenedithiolate) is the first three-dimensional single-component molecular metal. Structures and physical properties of analogous single-component molecular conductors [Ni(dmdt)2] (dmdt2-=dimethyltetrathiafulvalenedithiolate), [Ni(codt)2] (codt2-=ethylenedioxytetrathiafulvalenedithiolate) and [Pd(C3-tdt)2-] [(C3-tdt)2-= dipropylthiotetrathiafulvalenedithiolate] were examined. The structure of [Au(tmdt)2] was determined by synchrotron radiation powder diffraction experiments and the MEM/Rietveld analysis. The single-component paramagnetic molecule [Cu(dmdt)2] was also studied to clarify the possibility of single-component magnetic molecular conductors.",

keywords = "Diffraction and scattering, Electrocrystallization, Organic conductors based on radical cation and/or anion salts, X-ray emission",

author = "A. Kobayashi and W. Suzuki and E. Fujiwara and H. Tanaka and Y. Fujishiro and E. Nishibori and M. Takata and M. Sakata and Y. Okanao and H. Kobayashi",

year = "2003",

month = apr,

day = "4",

doi = "10.1016/S0379-6779(02)00703-8",

language = "English",

volume = "135-136",

pages = "511--513",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Development of single-component molecular metals based on extended-TTF dithiolate ligands

AU - Kobayashi, A.

AU - Suzuki, W.

AU - Fujiwara, E.

AU - Tanaka, H.

AU - Fujishiro, Y.

AU - Nishibori, E.

AU - Takata, M.

AU - Sakata, M.

AU - Okanao, Y.

AU - Kobayashi, H.

PY - 2003/4/4

Y1 - 2003/4/4

N2 - The novel nickel complex with the extended-TTF dithiolate ligand [Ni(tmdt)2] (tmdt2= trimethylenedithiotetrathiafulvalenedithiolate) is the first three-dimensional single-component molecular metal. Structures and physical properties of analogous single-component molecular conductors [Ni(dmdt)2] (dmdt2-=dimethyltetrathiafulvalenedithiolate), [Ni(codt)2] (codt2-=ethylenedioxytetrathiafulvalenedithiolate) and [Pd(C3-tdt)2-] [(C3-tdt)2-= dipropylthiotetrathiafulvalenedithiolate] were examined. The structure of [Au(tmdt)2] was determined by synchrotron radiation powder diffraction experiments and the MEM/Rietveld analysis. The single-component paramagnetic molecule [Cu(dmdt)2] was also studied to clarify the possibility of single-component magnetic molecular conductors.

AB - The novel nickel complex with the extended-TTF dithiolate ligand [Ni(tmdt)2] (tmdt2= trimethylenedithiotetrathiafulvalenedithiolate) is the first three-dimensional single-component molecular metal. Structures and physical properties of analogous single-component molecular conductors [Ni(dmdt)2] (dmdt2-=dimethyltetrathiafulvalenedithiolate), [Ni(codt)2] (codt2-=ethylenedioxytetrathiafulvalenedithiolate) and [Pd(C3-tdt)2-] [(C3-tdt)2-= dipropylthiotetrathiafulvalenedithiolate] were examined. The structure of [Au(tmdt)2] was determined by synchrotron radiation powder diffraction experiments and the MEM/Rietveld analysis. The single-component paramagnetic molecule [Cu(dmdt)2] was also studied to clarify the possibility of single-component magnetic molecular conductors.

KW - Diffraction and scattering

KW - Electrocrystallization

KW - Organic conductors based on radical cation and/or anion salts

KW - X-ray emission

UR - http://www.scopus.com/inward/record.url?scp=10344244382&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=10344244382&partnerID=8YFLogxK

U2 - 10.1016/S0379-6779(02)00703-8

DO - 10.1016/S0379-6779(02)00703-8

M3 - Article

AN - SCOPUS:10344244382

SN - 0379-6779

VL - 135-136

SP - 511

EP - 513

JO - Synthetic Metals

JF - Synthetic Metals

ER -

Development of single-component molecular metals based on extended-TTF dithiolate ligands

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this