Development of various metal sulfide photocatalysts consisting of d0, d5, and d10 metal ions for sacrificial H2 evolution under visible light irradiation

Tomoaki Takayama; Issei Tsuji; Naruhiko Aono; Masamitsu Harada; Tsutomu Okuda; Akihide Iwase; Hideki Kato; Akihiko Kudo

doi:10.1246/cl.161192

Development of various metal sulfide photocatalysts consisting of d⁰, d⁵, and d¹⁰ metal ions for sacrificial H₂ evolution under visible light irradiation

Tomoaki Takayama, Issei Tsuji, Naruhiko Aono, Masamitsu Harada, Tsutomu Okuda, Akihide Iwase, Hideki Kato, Akihiko Kudo

IMRAM - Division of Inorganic Material Research

Tokyo University of Science

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

We have developed metal sulfide photocatalysts with various crystal structures and constituent metal cations with d⁰, d⁵, and d¹⁰ electron configurations. Cu₃VS₄, Cu₃NbS₄, and Cu₃TaS₄ with a sulvanite structure, ZnGa_xIn_2-xS₄ (x = 0-0.6), and MnGaInS₄ with layered structures, BaLaCuS₃ with a one-dimensionally anisotropic structure along the b-axis, and a (ZnS)_0.9-(CuCl)_0.1 solid solution with a zinc blende structure have arisen as new photocatalysts for H₂ evolution in the presence of sacrificial electron donors under visible light irradiation.

Original language	English
Pages (from-to)	616-619
Number of pages	4
Journal	Chemistry Letters
Volume	46
Issue number	4
DOIs	https://doi.org/10.1246/cl.161192
Publication status	Published - 2017

Keywords

Hydrogen evolution
Metal sulfide photocatalyst
Visible light

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10.1246/cl.161192

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title = "Development of various metal sulfide photocatalysts consisting of d0, d5, and d10 metal ions for sacrificial H2 evolution under visible light irradiation",

abstract = "We have developed metal sulfide photocatalysts with various crystal structures and constituent metal cations with d0, d5, and d10 electron configurations. Cu3VS4, Cu3NbS4, and Cu3TaS4 with a sulvanite structure, ZnGaxIn2-xS4 (x = 0-0.6), and MnGaInS4 with layered structures, BaLaCuS3 with a one-dimensionally anisotropic structure along the b-axis, and a (ZnS)0.9-(CuCl)0.1 solid solution with a zinc blende structure have arisen as new photocatalysts for H2 evolution in the presence of sacrificial electron donors under visible light irradiation.",

keywords = "Hydrogen evolution, Metal sulfide photocatalyst, Visible light",

author = "Tomoaki Takayama and Issei Tsuji and Naruhiko Aono and Masamitsu Harada and Tsutomu Okuda and Akihide Iwase and Hideki Kato and Akihiko Kudo",

note = "Publisher Copyright: {\textcopyright} 2017 The Chemical Society of Japan.",

year = "2017",

doi = "10.1246/cl.161192",

language = "English",

volume = "46",

pages = "616--619",

journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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TY - JOUR

T1 - Development of various metal sulfide photocatalysts consisting of d0, d5, and d10 metal ions for sacrificial H2 evolution under visible light irradiation

AU - Takayama, Tomoaki

AU - Tsuji, Issei

AU - Aono, Naruhiko

AU - Harada, Masamitsu

AU - Okuda, Tsutomu

AU - Iwase, Akihide

AU - Kato, Hideki

AU - Kudo, Akihiko

PY - 2017

Y1 - 2017

N2 - We have developed metal sulfide photocatalysts with various crystal structures and constituent metal cations with d0, d5, and d10 electron configurations. Cu3VS4, Cu3NbS4, and Cu3TaS4 with a sulvanite structure, ZnGaxIn2-xS4 (x = 0-0.6), and MnGaInS4 with layered structures, BaLaCuS3 with a one-dimensionally anisotropic structure along the b-axis, and a (ZnS)0.9-(CuCl)0.1 solid solution with a zinc blende structure have arisen as new photocatalysts for H2 evolution in the presence of sacrificial electron donors under visible light irradiation.

AB - We have developed metal sulfide photocatalysts with various crystal structures and constituent metal cations with d0, d5, and d10 electron configurations. Cu3VS4, Cu3NbS4, and Cu3TaS4 with a sulvanite structure, ZnGaxIn2-xS4 (x = 0-0.6), and MnGaInS4 with layered structures, BaLaCuS3 with a one-dimensionally anisotropic structure along the b-axis, and a (ZnS)0.9-(CuCl)0.1 solid solution with a zinc blende structure have arisen as new photocatalysts for H2 evolution in the presence of sacrificial electron donors under visible light irradiation.

KW - Hydrogen evolution

KW - Metal sulfide photocatalyst

KW - Visible light

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DO - 10.1246/cl.161192

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VL - 46

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 4

ER -

Development of various metal sulfide photocatalysts consisting of d⁰, d⁵, and d¹⁰ metal ions for sacrificial H₂ evolution under visible light irradiation

Abstract

Keywords

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