TY - JOUR
T1 - Diastereomer effects on antiferroelectricity and ferroelectricity of the newly synthesized liquid crystals
AU - Kobayashi, Ichiro
AU - Suzuki, Yoshiichi
AU - Yajima, Tomoko
AU - Kawauchi, Susumu
AU - Terada, Masahiro
AU - Mikami, Koichi
PY - 1997
Y1 - 1997
N2 - Using the novel-model liquid crystals (LC) having two stereogenic centers in the molecule (CF3 and CH3), which were synthesized by the chiral titanium complex-catalyzed carbonyl-ene reaction with fluoral, the relationship between the appearance of antiferroelectricity and conformational arrangement were examined. From the results of our investigation, we concluded that the relative stereochemistry of the diastereomeric chiral portion should give strong effect on the preference and the thermotropic stability of SmCa* phase.
AB - Using the novel-model liquid crystals (LC) having two stereogenic centers in the molecule (CF3 and CH3), which were synthesized by the chiral titanium complex-catalyzed carbonyl-ene reaction with fluoral, the relationship between the appearance of antiferroelectricity and conformational arrangement were examined. From the results of our investigation, we concluded that the relative stereochemistry of the diastereomeric chiral portion should give strong effect on the preference and the thermotropic stability of SmCa* phase.
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U2 - 10.1080/10587259708039421
DO - 10.1080/10587259708039421
M3 - Article
AN - SCOPUS:0003049855
SN - 1058-725X
VL - 303
SP - 165
EP - 170
JO - Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals
ER -