Diastereoselective hydroformylation of certain protected allylic alcohols

Takayuki Doi; Hiroshi Komatsu; Keiji Yamamoto

doi:10.1016/0040-4039(96)01502-X

Diastereoselective hydroformylation of certain protected allylic alcohols

Takayuki Doi, Hiroshi Komatsu, Keiji Yamamoto

PHA - Molecular Pharmaceutical Science

Tokyo Institute of Technology

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The diastereoselective hydroformylation of 2-methyl-1-alken-3-ol and 5-t-butyl-2-methylene-cyclohexanol derivatives gave threo- and erythroy-γ-hydroxyalkanal derivatives in ratios up to 82:18, contrary to the results observed for hydroxy-directed hydrogenation of the corresponding allylic alcohols.

Original language	English
Pages (from-to)	6877-6880
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	38
DOIs	https://doi.org/10.1016/0040-4039(96)01502-X
Publication status	Published - 1996 Sept 16

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title = "Diastereoselective hydroformylation of certain protected allylic alcohols",

abstract = "The diastereoselective hydroformylation of 2-methyl-1-alken-3-ol and 5-t-butyl-2-methylene-cyclohexanol derivatives gave threo- and erythroy-γ-hydroxyalkanal derivatives in ratios up to 82:18, contrary to the results observed for hydroxy-directed hydrogenation of the corresponding allylic alcohols.",

author = "Takayuki Doi and Hiroshi Komatsu and Keiji Yamamoto",

year = "1996",

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T1 - Diastereoselective hydroformylation of certain protected allylic alcohols

AU - Doi, Takayuki

AU - Komatsu, Hiroshi

AU - Yamamoto, Keiji

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Y1 - 1996/9/16

N2 - The diastereoselective hydroformylation of 2-methyl-1-alken-3-ol and 5-t-butyl-2-methylene-cyclohexanol derivatives gave threo- and erythroy-γ-hydroxyalkanal derivatives in ratios up to 82:18, contrary to the results observed for hydroxy-directed hydrogenation of the corresponding allylic alcohols.

AB - The diastereoselective hydroformylation of 2-methyl-1-alken-3-ol and 5-t-butyl-2-methylene-cyclohexanol derivatives gave threo- and erythroy-γ-hydroxyalkanal derivatives in ratios up to 82:18, contrary to the results observed for hydroxy-directed hydrogenation of the corresponding allylic alcohols.

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M3 - Article

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 38

ER -

Diastereoselective hydroformylation of certain protected allylic alcohols

Abstract

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