Directed assembly of nanoscale Co(II)-substituted (Co9[P2W15]3) and (Co14[P2W15]4) polyoxometalates

Claire Lydon; Mercè Martin Sabi; Mark D. Symes; De Liang Long; Mark Murrie; Shunsuke Yoshii; Hiroyuki Nojiri; Leroy Cronin

doi:10.1039/c2cc34865a

Directed assembly of nanoscale Co(II)-substituted (Co₉[P₂W₁₅]₃) and (Co₁₄[P₂W₁₅]₄) polyoxometalates

Claire Lydon, Mercè Martin Sabi, Mark D. Symes, De Liang Long, Mark Murrie, Shunsuke Yoshii, Hiroyuki Nojiri, Leroy Cronin

IMR - Institute for Materials Research (institute affiliation only)

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

Herein we report two structurally intriguing Co(II)-substituted polyoxometalates, a (Co₉[P₂W₁₅]₃) and (Co₁₄[P₂W₁₅]₄) (compounds 1 and 2) that are formed from the same building blocks under subtly different conditions. Compound 1 displays a structure previously predicted but never before realised, whilst compound 2 is the first Co-containing Dawson-based single-molecule magnet and has a unique cruciform structure.

Original language	English
Pages (from-to)	9819-9821
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	79
DOIs	https://doi.org/10.1039/c2cc34865a
Publication status	Published - 2012 Sept 10

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abstract = "Herein we report two structurally intriguing Co(II)-substituted polyoxometalates, a (Co9[P2W15]3) and (Co14[P2W15]4) (compounds 1 and 2) that are formed from the same building blocks under subtly different conditions. Compound 1 displays a structure previously predicted but never before realised, whilst compound 2 is the first Co-containing Dawson-based single-molecule magnet and has a unique cruciform structure.",

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T1 - Directed assembly of nanoscale Co(II)-substituted (Co9[P2W15]3) and (Co14[P2W15]4) polyoxometalates

AU - Lydon, Claire

AU - Sabi, Mercè Martin

AU - Symes, Mark D.

AU - Long, De Liang

AU - Murrie, Mark

AU - Yoshii, Shunsuke

AU - Nojiri, Hiroyuki

AU - Cronin, Leroy

PY - 2012/9/10

Y1 - 2012/9/10

N2 - Herein we report two structurally intriguing Co(II)-substituted polyoxometalates, a (Co9[P2W15]3) and (Co14[P2W15]4) (compounds 1 and 2) that are formed from the same building blocks under subtly different conditions. Compound 1 displays a structure previously predicted but never before realised, whilst compound 2 is the first Co-containing Dawson-based single-molecule magnet and has a unique cruciform structure.

AB - Herein we report two structurally intriguing Co(II)-substituted polyoxometalates, a (Co9[P2W15]3) and (Co14[P2W15]4) (compounds 1 and 2) that are formed from the same building blocks under subtly different conditions. Compound 1 displays a structure previously predicted but never before realised, whilst compound 2 is the first Co-containing Dawson-based single-molecule magnet and has a unique cruciform structure.

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ER -

Directed assembly of nanoscale Co(II)-substituted (Co₉[P₂W₁₅]₃) and (Co₁₄[P₂W₁₅]₄) polyoxometalates

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