Doping effect of nonmagnetic impurity on the spin-Peierls-like transition in the quasi-one-dimensional (quasi-1D) spin system of 1-(4′-nitrobenzyl)pyridinium bis(maleonitriledithiolato)nickelate

Xiao Ming Ren; Guang Xiang Liu; Heng Xu; Tomoyuki Akutagawa; Takayoshi Nakamura

doi:10.1016/j.poly.2009.02.008

Doping effect of nonmagnetic impurity on the spin-Peierls-like transition in the quasi-one-dimensional (quasi-1D) spin system of 1-(4′-nitrobenzyl)pyridinium bis(maleonitriledithiolato)nickelate

Xiao Ming Ren, Guang Xiang Liu, Heng Xu, Tomoyuki Akutagawa, Takayoshi Nakamura

IMRAM - Materials-Measurement Hybrid Research Center

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A nonmagnetic compound, [NO₂BzPy][Cu(mnt)₂] (mnt^2- = maleonitriledithiolate; NO₂BzPy⁺ = 1-(4′-nitrobenzyl)pyridinium), is isostructural with [NO₂BzPy][Ni(mnt)₂], which is a quasi-1D spin system and exhibits a spin-Peierls-like transition with J = 192 K in the gapless state and spin energy gap = 738 K in the dimerization state, respectively. Further, five nonmagnetic impurity doped compounds [NO₂BzPy][Cu_xNi_1-x(mnt)₂] (x = 0.04-0.74) were prepared, and their crystal structures as well as magnetic properties were investigated. The nonmagnetic doping causes the suppression of the spin transition with an average rate of 139(13) K/percentage of dopant concentration, and the transition collapse is estimated at around x > 0.5.

Original language	English
Pages (from-to)	2075-2079
Number of pages	5
Journal	Polyhedron
Volume	28
Issue number	9-10
DOIs	https://doi.org/10.1016/j.poly.2009.02.008
Publication status	Published - 2009 Jun 22

Keywords

Bis(maleonitriledithiolato)nickelate
Crystal structure
Magnetic property
Nonmagnetic doping
Spin-Peierls-like transition

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10.1016/j.poly.2009.02.008

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@article{ae1a4c0841704850b632718c90c44b99,

title = "Doping effect of nonmagnetic impurity on the spin-Peierls-like transition in the quasi-one-dimensional (quasi-1D) spin system of 1-(4′-nitrobenzyl)pyridinium bis(maleonitriledithiolato)nickelate",

abstract = "A nonmagnetic compound, [NO2BzPy][Cu(mnt)2] (mnt2- = maleonitriledithiolate; NO2BzPy+ = 1-(4′-nitrobenzyl)pyridinium), is isostructural with [NO2BzPy][Ni(mnt)2], which is a quasi-1D spin system and exhibits a spin-Peierls-like transition with J = 192 K in the gapless state and spin energy gap = 738 K in the dimerization state, respectively. Further, five nonmagnetic impurity doped compounds [NO2BzPy][CuxNi1-x(mnt)2] (x = 0.04-0.74) were prepared, and their crystal structures as well as magnetic properties were investigated. The nonmagnetic doping causes the suppression of the spin transition with an average rate of 139(13) K/percentage of dopant concentration, and the transition collapse is estimated at around x > 0.5.",

keywords = "Bis(maleonitriledithiolato)nickelate, Crystal structure, Magnetic property, Nonmagnetic doping, Spin-Peierls-like transition",

author = "Ren, {Xiao Ming} and Liu, {Guang Xiang} and Heng Xu and Tomoyuki Akutagawa and Takayoshi Nakamura",

note = "Funding Information: X.M. Ren thanks the Natural Science Foundation for Outstanding Scholars of Anhui Province, PR China (Grant Nos. 044-J-04011 and 2005hbz20).",

year = "2009",

month = jun,

day = "22",

doi = "10.1016/j.poly.2009.02.008",

language = "English",

volume = "28",

pages = "2075--2079",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "9-10",

}

Doping effect of nonmagnetic impurity on the spin-Peierls-like transition in the quasi-one-dimensional (quasi-1D) spin system of 1-(4′-nitrobenzyl)pyridinium bis(maleonitriledithiolato)nickelate. / Ren, Xiao Ming; Liu, Guang Xiang; Xu, Heng et al.
In: Polyhedron, Vol. 28, No. 9-10, 22.06.2009, p. 2075-2079.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Doping effect of nonmagnetic impurity on the spin-Peierls-like transition in the quasi-one-dimensional (quasi-1D) spin system of 1-(4′-nitrobenzyl)pyridinium bis(maleonitriledithiolato)nickelate

AU - Ren, Xiao Ming

AU - Liu, Guang Xiang

AU - Xu, Heng

AU - Akutagawa, Tomoyuki

AU - Nakamura, Takayoshi

N1 - Funding Information: X.M. Ren thanks the Natural Science Foundation for Outstanding Scholars of Anhui Province, PR China (Grant Nos. 044-J-04011 and 2005hbz20).

PY - 2009/6/22

Y1 - 2009/6/22

N2 - A nonmagnetic compound, [NO2BzPy][Cu(mnt)2] (mnt2- = maleonitriledithiolate; NO2BzPy+ = 1-(4′-nitrobenzyl)pyridinium), is isostructural with [NO2BzPy][Ni(mnt)2], which is a quasi-1D spin system and exhibits a spin-Peierls-like transition with J = 192 K in the gapless state and spin energy gap = 738 K in the dimerization state, respectively. Further, five nonmagnetic impurity doped compounds [NO2BzPy][CuxNi1-x(mnt)2] (x = 0.04-0.74) were prepared, and their crystal structures as well as magnetic properties were investigated. The nonmagnetic doping causes the suppression of the spin transition with an average rate of 139(13) K/percentage of dopant concentration, and the transition collapse is estimated at around x > 0.5.

AB - A nonmagnetic compound, [NO2BzPy][Cu(mnt)2] (mnt2- = maleonitriledithiolate; NO2BzPy+ = 1-(4′-nitrobenzyl)pyridinium), is isostructural with [NO2BzPy][Ni(mnt)2], which is a quasi-1D spin system and exhibits a spin-Peierls-like transition with J = 192 K in the gapless state and spin energy gap = 738 K in the dimerization state, respectively. Further, five nonmagnetic impurity doped compounds [NO2BzPy][CuxNi1-x(mnt)2] (x = 0.04-0.74) were prepared, and their crystal structures as well as magnetic properties were investigated. The nonmagnetic doping causes the suppression of the spin transition with an average rate of 139(13) K/percentage of dopant concentration, and the transition collapse is estimated at around x > 0.5.

KW - Bis(maleonitriledithiolato)nickelate

KW - Crystal structure

KW - Magnetic property

KW - Nonmagnetic doping

KW - Spin-Peierls-like transition

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U2 - 10.1016/j.poly.2009.02.008

DO - 10.1016/j.poly.2009.02.008

M3 - Article

AN - SCOPUS:66149174776

SN - 0277-5387

VL - 28

SP - 2075

EP - 2079

JO - Polyhedron

JF - Polyhedron

IS - 9-10

ER -

Doping effect of nonmagnetic impurity on the spin-Peierls-like transition in the quasi-one-dimensional (quasi-1D) spin system of 1-(4′-nitrobenzyl)pyridinium bis(maleonitriledithiolato)nickelate

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