TY - JOUR
T1 - Effect of functional groups in MIL-101 on water sorption behavior
AU - Akiyama, George
AU - Matsuda, Ryotaro
AU - Sato, Hiroshi
AU - Hori, Akihiro
AU - Takata, Masaki
AU - Kitagawa, Susumu
PY - 2012/7/15
Y1 - 2012/7/15
N2 - Four MIL-101-type porous coordination polymers were synthesized containing different substituents (-H, -NO 2, -NH 2, -SO 3H) in the ligand and their water sorption properties were investigated. All of the compounds adsorbed huge amounts of water (ca. 0.8-1.2 g g -1) and the adsorbed water can be released at relatively low temperatures (ca. 353 K). In addition, the trapping pressure of water adsorption was found to be controlled by changing the substituents, varying the hydrophobicity of the functional groups.
AB - Four MIL-101-type porous coordination polymers were synthesized containing different substituents (-H, -NO 2, -NH 2, -SO 3H) in the ligand and their water sorption properties were investigated. All of the compounds adsorbed huge amounts of water (ca. 0.8-1.2 g g -1) and the adsorbed water can be released at relatively low temperatures (ca. 353 K). In addition, the trapping pressure of water adsorption was found to be controlled by changing the substituents, varying the hydrophobicity of the functional groups.
KW - Heat transformation
KW - Metal-organic framework
KW - Porous coordination polymer
KW - Water adsorption
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U2 - 10.1016/j.micromeso.2012.01.015
DO - 10.1016/j.micromeso.2012.01.015
M3 - Article
AN - SCOPUS:84861185764
SN - 1387-1811
VL - 157
SP - 89
EP - 93
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
ER -