Abstract
Angular correlation of annihilation radiation (ACAR) from single crystals of [Fe(ptz)6](BF4)2 and [Zn(ptz)6](BF4)2 were measured in the temperature range between 23K and 295K. Large temperature dependence of ACAR spectra for [Fe(ptz)6](BF4)2 around the spin-crossover temperature (130K) was observed. On the contrary, ACAR spectra for [Zn(ptz)6](BF4)2 was almost independent of temperature. The results show that the positronium atom is highly sensitive probe of the spin-crossover transition.
Original language | English |
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Pages (from-to) | 765-768 |
Number of pages | 4 |
Journal | Materials Science Forum |
Volume | 175-178 |
Issue number | pt 2 |
Publication status | Published - 1995 Jan 1 |
Externally published | Yes |
Event | Proceedings of the 10th International Conference on Positron Annihilation. Part 1 (of 2) - Beijing, China Duration: 1994 May 23 → 1994 May 29 |
ASJC Scopus subject areas
- Materials Science(all)