Electrical conduction of halogen-bridged metal complexes Ni 1-xPdx(chxn)2Br3

Hiroshi Ito; Makoto Sunata; Shin Ichi Kuroda; Toshio Manabe; Masahiro Yamashita

Electrical conduction of halogen-bridged metal complexes Ni _1-xPd_x(chxn)₂Br₃

Hiroshi Ito, Makoto Sunata, Shin Ichi Kuroda, Toshio Manabe, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

Abstract

The resistance and thermopower of the quasi-one-dimensional halogen-bridged metal complexes Ni_1-xPd_x(chxn)₂Br₃ are studied. Pressure dependence of the resistance indicates the crossover from SDW state to CDW state at x=0.84-0.95. For almost all x region, thermopower is negative. For x<0.5, thermopower is independent of temperature, while it is semiconducting for x>0.6.

Original language	English
Pages (from-to)	285-290
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	379
Publication status	Published - 2002 Dec 1
Externally published	Yes

Keywords

Anisotropy
Halogen-bridged metal complex
Pressure
Resistance
Thermopower

ASJC Scopus subject areas

Condensed Matter Physics

Cite this

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title = "Electrical conduction of halogen-bridged metal complexes Ni 1-xPdx(chxn)2Br3",

abstract = "The resistance and thermopower of the quasi-one-dimensional halogen-bridged metal complexes Ni1-xPdx(chxn)2Br3 are studied. Pressure dependence of the resistance indicates the crossover from SDW state to CDW state at x=0.84-0.95. For almost all x region, thermopower is negative. For x<0.5, thermopower is independent of temperature, while it is semiconducting for x>0.6.",

keywords = "Anisotropy, Halogen-bridged metal complex, Pressure, Resistance, Thermopower",

author = "Hiroshi Ito and Makoto Sunata and Kuroda, {Shin Ichi} and Toshio Manabe and Masahiro Yamashita",

year = "2002",

month = dec,

day = "1",

language = "English",

volume = "379",

pages = "285--290",

journal = "Molecular Crystals and Liquid Crystals",

issn = "1542-1406",

publisher = "Taylor and Francis Ltd.",

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TY - JOUR

T1 - Electrical conduction of halogen-bridged metal complexes Ni 1-xPdx(chxn)2Br3

AU - Ito, Hiroshi

AU - Sunata, Makoto

AU - Kuroda, Shin Ichi

AU - Manabe, Toshio

AU - Yamashita, Masahiro

PY - 2002/12/1

Y1 - 2002/12/1

N2 - The resistance and thermopower of the quasi-one-dimensional halogen-bridged metal complexes Ni1-xPdx(chxn)2Br3 are studied. Pressure dependence of the resistance indicates the crossover from SDW state to CDW state at x=0.84-0.95. For almost all x region, thermopower is negative. For x<0.5, thermopower is independent of temperature, while it is semiconducting for x>0.6.

AB - The resistance and thermopower of the quasi-one-dimensional halogen-bridged metal complexes Ni1-xPdx(chxn)2Br3 are studied. Pressure dependence of the resistance indicates the crossover from SDW state to CDW state at x=0.84-0.95. For almost all x region, thermopower is negative. For x<0.5, thermopower is independent of temperature, while it is semiconducting for x>0.6.

KW - Anisotropy

KW - Halogen-bridged metal complex

KW - Pressure

KW - Resistance

KW - Thermopower

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M3 - Article

AN - SCOPUS:3142713124

SN - 1542-1406

VL - 379

SP - 285

EP - 290

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

ER -

Electrical conduction of halogen-bridged metal complexes Ni _1-xPd_x(chxn)₂Br₃

Abstract

Keywords

ASJC Scopus subject areas

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