TY - JOUR
T1 - Electrochemical behavior of titanium ions in various molten alkali chlorides
AU - Song, Jianxun
AU - Xiao, Jiusan
AU - Zhu, Hongmin
N1 - Publisher Copyright:
© 2017 The Electrochemical Society. All rights reserved.
PY - 2017
Y1 - 2017
N2 - Cyclic voltammetry and square wave voltammetry were performed for TiCl3 at 1023 K, in molten LiCl, LiCl-KCl, NaCl-CsCl and CsCl, respectively. The anodic process from Ti(III) to Ti(IV) is a simple reversible process in all the alkali chloride melts. Ti(III) can be reduced directly to Ti in one step, in CsCl, while Ti(II) will appear before Ti in LiCl, LiCl-KCl and NaCl-CsCl. The electrode potentials of redox couples of titanium species decrease with the decrease of the polarization power of solvent alkali ion.
AB - Cyclic voltammetry and square wave voltammetry were performed for TiCl3 at 1023 K, in molten LiCl, LiCl-KCl, NaCl-CsCl and CsCl, respectively. The anodic process from Ti(III) to Ti(IV) is a simple reversible process in all the alkali chloride melts. Ti(III) can be reduced directly to Ti in one step, in CsCl, while Ti(II) will appear before Ti in LiCl, LiCl-KCl and NaCl-CsCl. The electrode potentials of redox couples of titanium species decrease with the decrease of the polarization power of solvent alkali ion.
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U2 - 10.1149/2.0781712jes
DO - 10.1149/2.0781712jes
M3 - Article
AN - SCOPUS:85031010980
SN - 0013-4651
VL - 164
SP - E321-E325
JO - Journal of the Electrochemical Society
JF - Journal of the Electrochemical Society
IS - 12
ER -
