Electrochemical preparation of an electroactive polymer poly(dodecyloxy dibenzothiophene) (polyDDBTh) from hydroxyl dibenzothiophene (HDBTh) as a bioconverted monomer

Hiromasa Goto; Yong Soo Jeong; Kohsuke Kawabata; Masaki Takada; Takuya Kotanagi; Hideyuki Shigemori; Nobuhiko Nomura

doi:10.1007/s10800-009-9994-z

Electrochemical preparation of an electroactive polymer poly(dodecyloxy dibenzothiophene) (polyDDBTh) from hydroxyl dibenzothiophene (HDBTh) as a bioconverted monomer

Hiromasa Goto, Yong Soo Jeong, Kohsuke Kawabata, Masaki Takada, Takuya Kotanagi, Hideyuki Shigemori, Nobuhiko Nomura

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A combination of biotechnological and electrochemical techniques is employed to synthesize an electroactive π-conjugated polymer. The monomer precursor bearing a hydroxyl group is obtained by the bioconversion of dibenzothiophene. An alkyl chain substituent is introduced by Williamson etherification with the aid of crown ether, and electrochemical polymerization is carried out by repeated potential scanning of the monomer in an electrolytic reaction solution. The polymer film thus prepared is shown to exhibit good electroactive characteristics.

Original language	English
Pages (from-to)	191-195
Number of pages	5
Journal	Journal of Applied Electrochemistry
Volume	40
Issue number	1
DOIs	https://doi.org/10.1007/s10800-009-9994-z
Publication status	Published - 2010 Jan
Externally published	Yes

Keywords

Bioconversion
Electroactive polymer
Electrolytic polymerization
Petroleum pitch
π-conjugated polymer

ASJC Scopus subject areas

Chemical Engineering(all)
Electrochemistry
Materials Chemistry

Access to Document

10.1007/s10800-009-9994-z

Cite this

Electrochemical preparation of an electroactive polymer poly(dodecyloxy dibenzothiophene) (polyDDBTh) from hydroxyl dibenzothiophene (HDBTh) as a bioconverted monomer. / Goto, Hiromasa; Jeong, Yong Soo; Kawabata, Kohsuke et al.
In: Journal of Applied Electrochemistry, Vol. 40, No. 1, 01.2010, p. 191-195.

Research output: Contribution to journal › Article › peer-review

@article{cb2e5809fdb2460383f56799037d9e99,

title = "Electrochemical preparation of an electroactive polymer poly(dodecyloxy dibenzothiophene) (polyDDBTh) from hydroxyl dibenzothiophene (HDBTh) as a bioconverted monomer",

abstract = "A combination of biotechnological and electrochemical techniques is employed to synthesize an electroactive π-conjugated polymer. The monomer precursor bearing a hydroxyl group is obtained by the bioconversion of dibenzothiophene. An alkyl chain substituent is introduced by Williamson etherification with the aid of crown ether, and electrochemical polymerization is carried out by repeated potential scanning of the monomer in an electrolytic reaction solution. The polymer film thus prepared is shown to exhibit good electroactive characteristics.",

keywords = "Bioconversion, Electroactive polymer, Electrolytic polymerization, Petroleum pitch, π-conjugated polymer",

author = "Hiromasa Goto and Jeong, {Yong Soo} and Kohsuke Kawabata and Masaki Takada and Takuya Kotanagi and Hideyuki Shigemori and Nobuhiko Nomura",

year = "2010",

month = jan,

doi = "10.1007/s10800-009-9994-z",

language = "English",

volume = "40",

pages = "191--195",

journal = "Journal of Applied Electrochemistry",

issn = "0021-891X",

publisher = "Springer Netherlands",

number = "1",

}

TY - JOUR

T1 - Electrochemical preparation of an electroactive polymer poly(dodecyloxy dibenzothiophene) (polyDDBTh) from hydroxyl dibenzothiophene (HDBTh) as a bioconverted monomer

AU - Goto, Hiromasa

AU - Jeong, Yong Soo

AU - Kawabata, Kohsuke

AU - Takada, Masaki

AU - Kotanagi, Takuya

AU - Shigemori, Hideyuki

AU - Nomura, Nobuhiko

PY - 2010/1

Y1 - 2010/1

N2 - A combination of biotechnological and electrochemical techniques is employed to synthesize an electroactive π-conjugated polymer. The monomer precursor bearing a hydroxyl group is obtained by the bioconversion of dibenzothiophene. An alkyl chain substituent is introduced by Williamson etherification with the aid of crown ether, and electrochemical polymerization is carried out by repeated potential scanning of the monomer in an electrolytic reaction solution. The polymer film thus prepared is shown to exhibit good electroactive characteristics.

AB - A combination of biotechnological and electrochemical techniques is employed to synthesize an electroactive π-conjugated polymer. The monomer precursor bearing a hydroxyl group is obtained by the bioconversion of dibenzothiophene. An alkyl chain substituent is introduced by Williamson etherification with the aid of crown ether, and electrochemical polymerization is carried out by repeated potential scanning of the monomer in an electrolytic reaction solution. The polymer film thus prepared is shown to exhibit good electroactive characteristics.

KW - Bioconversion

KW - Electroactive polymer

KW - Electrolytic polymerization

KW - Petroleum pitch

KW - π-conjugated polymer

UR - http://www.scopus.com/inward/record.url?scp=73349138563&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=73349138563&partnerID=8YFLogxK

U2 - 10.1007/s10800-009-9994-z

DO - 10.1007/s10800-009-9994-z

M3 - Article

AN - SCOPUS:73349138563

SN - 0021-891X

VL - 40

SP - 191

EP - 195

JO - Journal of Applied Electrochemistry

JF - Journal of Applied Electrochemistry

IS - 1

ER -

Electrochemical preparation of an electroactive polymer poly(dodecyloxy dibenzothiophene) (polyDDBTh) from hydroxyl dibenzothiophene (HDBTh) as a bioconverted monomer

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this