Electrochemical synthesis and structure of the first example of a ferrocene dication: Propane-1,3-diyl-1,1′-bis(tetramethylcyclopentadienyl)iron(2+)

Hiroshi Ogino; Hiromi Tobita; Hiroki Habazaki; Mamoru Shimoi

doi:10.1039/C39890000828

Electrochemical synthesis and structure of the first example of a ferrocene dication: Propane-1,3-diyl-1,1′-bis(tetramethylcyclopentadienyl)iron(2+)

Hiroshi Ogino, Hiromi Tobita, Hiroki Habazaki, Mamoru Shimoi

Institute for Excellence in Higher Education (IEHE) (organization affiliation only)

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The permethylferrocenophane [(pdmcp)Fe] [pdmcp = η⁵, η⁵-C₅Me₄(CH₂)₃C ₅Me₄] and its oxidised species, monocation and dication salts, were synthesised, in which the latter, [(pdmcp)Fe(NCMe)](PF ₆)₂, has a substantially bent bis(cyclopentadienyl) moiety to accommodate one molecule of MeCN.

Original language	English
Pages (from-to)	828-829
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/C39890000828
Publication status	Published - 1989 Jan 1

ASJC Scopus subject areas

Molecular Medicine

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Electrochemical synthesis and structure of the first example of a ferrocene dication: Propane-1,3-diyl-1,1′-bis(tetramethylcyclopentadienyl)iron(2+). / Ogino, Hiroshi; Tobita, Hiromi; Habazaki, Hiroki et al.
In: Journal of the Chemical Society, Chemical Communications, No. 13, 01.01.1989, p. 828-829.

Research output: Contribution to journal › Article › peer-review

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Electrochemical synthesis and structure of the first example of a ferrocene dication: Propane-1,3-diyl-1,1′-bis(tetramethylcyclopentadienyl)iron(2+)

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