Electronic phase transition of BEDT-TTF based mixed-stack charge-transfer complexes

T. Hasegawa; T. Akutagawa; T. Nakamura; Y. Sasou; R. Kondo; S. Kagoshima; T. Mochida; G. Saito; Y. Iwasa

doi:10.1016/S0379-6779(98)00443-3

Electronic phase transition of BEDT-TTF based mixed-stack charge-transfer complexes

T. Hasegawa, T. Akutagawa, T. Nakamura, Y. Sasou, R. Kondo, S. Kagoshima, T. Mochida, G. Saito, Y. Iwasa

IMRAM - Materials-Measurement Hybrid Research Center

Research output: Contribution to journal › Conference article › peer-review

4 Citations (Scopus)

Abstract

The BEDT-TTF based mixed-stack charge-transfer (CT) complexes have been investigated for a series of isostructural compounds. The ionic complex of (BEDO-TTF)(Cl₂TCNQ) is a magnetic insulator with showing Curie-Weiss behavior in magnetic susceptibility, in sharp contrast to the conventional mixed-stack CT complexes. The (BEDT-TTF)(ClMeTCNQ) compound undergoes neutral-ionic (NI) phase transition at high pressure.

Original language	English
Pages (from-to)	1804-1805
Number of pages	2
Journal	Synthetic Metals
Volume	103
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(98)00443-3
Publication status	Published - 1999 Jun 24
Event	Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier Duration: 1998 Jul 12 → 1998 Jul 18

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title = "Electronic phase transition of BEDT-TTF based mixed-stack charge-transfer complexes",

abstract = "The BEDT-TTF based mixed-stack charge-transfer (CT) complexes have been investigated for a series of isostructural compounds. The ionic complex of (BEDO-TTF)(Cl2TCNQ) is a magnetic insulator with showing Curie-Weiss behavior in magnetic susceptibility, in sharp contrast to the conventional mixed-stack CT complexes. The (BEDT-TTF)(ClMeTCNQ) compound undergoes neutral-ionic (NI) phase transition at high pressure.",

author = "T. Hasegawa and T. Akutagawa and T. Nakamura and Y. Sasou and R. Kondo and S. Kagoshima and T. Mochida and G. Saito and Y. Iwasa",

note = "Funding Information: This work is supported by a Research-Grant-in Aid from the Ministry of Education, Science and Culture of Japan.; Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) ; Conference date: 12-07-1998 Through 18-07-1998",

year = "1999",

month = jun,

day = "24",

doi = "10.1016/S0379-6779(98)00443-3",

language = "English",

volume = "103",

pages = "1804--1805",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "1-3",

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TY - JOUR

T1 - Electronic phase transition of BEDT-TTF based mixed-stack charge-transfer complexes

AU - Hasegawa, T.

AU - Akutagawa, T.

AU - Nakamura, T.

AU - Sasou, Y.

AU - Kondo, R.

AU - Kagoshima, S.

AU - Mochida, T.

AU - Saito, G.

AU - Iwasa, Y.

N1 - Funding Information: This work is supported by a Research-Grant-in Aid from the Ministry of Education, Science and Culture of Japan.

PY - 1999/6/24

Y1 - 1999/6/24

N2 - The BEDT-TTF based mixed-stack charge-transfer (CT) complexes have been investigated for a series of isostructural compounds. The ionic complex of (BEDO-TTF)(Cl2TCNQ) is a magnetic insulator with showing Curie-Weiss behavior in magnetic susceptibility, in sharp contrast to the conventional mixed-stack CT complexes. The (BEDT-TTF)(ClMeTCNQ) compound undergoes neutral-ionic (NI) phase transition at high pressure.

AB - The BEDT-TTF based mixed-stack charge-transfer (CT) complexes have been investigated for a series of isostructural compounds. The ionic complex of (BEDO-TTF)(Cl2TCNQ) is a magnetic insulator with showing Curie-Weiss behavior in magnetic susceptibility, in sharp contrast to the conventional mixed-stack CT complexes. The (BEDT-TTF)(ClMeTCNQ) compound undergoes neutral-ionic (NI) phase transition at high pressure.

UR - http://www.scopus.com/inward/record.url?scp=0033138295&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033138295&partnerID=8YFLogxK

U2 - 10.1016/S0379-6779(98)00443-3

DO - 10.1016/S0379-6779(98)00443-3

M3 - Conference article

AN - SCOPUS:0033138295

SN - 0379-6779

VL - 103

SP - 1804

EP - 1805

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

T2 - Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98)

Y2 - 12 July 1998 through 18 July 1998

ER -

Electronic phase transition of BEDT-TTF based mixed-stack charge-transfer complexes

Abstract

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