Electrophilic aromatic substitution of arenes with CO 2 mediated by R3SiB(C 6F 5) 4

Megumi Konno; Masafumi Chiba; Koji Nemoto; Tetsutaro Hattori

doi:10.1246/cl.2012.913

Electrophilic aromatic substitution of arenes with CO ₂ mediated by R3SiB(C ₆F ₅) ₄

Megumi Konno, Masafumi Chiba, Koji Nemoto, Tetsutaro Hattori

ENG - Biomolecular Engineering

Tohoku University

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The FriedelCrafts- type carboxylation of arenes has been achieved by activating CO ₂ with silylium borates. The reaction exhibits broader substrate applicability than does our previously reported AlX ₃/R ₃SiX-mediated carboxylation.

Original language	English
Pages (from-to)	913-914
Number of pages	2
Journal	Chemistry Letters
Volume	41
Issue number	9
DOIs	https://doi.org/10.1246/cl.2012.913
Publication status	Published - 2012

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title = "Electrophilic aromatic substitution of arenes with CO 2 mediated by R3SiB(C 6F 5) 4 ",

abstract = "The FriedelCrafts- type carboxylation of arenes has been achieved by activating CO 2 with silylium borates. The reaction exhibits broader substrate applicability than does our previously reported AlX 3/R 3SiX-mediated carboxylation.",

author = "Megumi Konno and Masafumi Chiba and Koji Nemoto and Tetsutaro Hattori",

year = "2012",

doi = "10.1246/cl.2012.913",

language = "English",

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pages = "913--914",

journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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T1 - Electrophilic aromatic substitution of arenes with CO 2 mediated by R3SiB(C 6F 5) 4

AU - Konno, Megumi

AU - Chiba, Masafumi

AU - Nemoto, Koji

AU - Hattori, Tetsutaro

PY - 2012

Y1 - 2012

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AB - The FriedelCrafts- type carboxylation of arenes has been achieved by activating CO 2 with silylium borates. The reaction exhibits broader substrate applicability than does our previously reported AlX 3/R 3SiX-mediated carboxylation.

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SN - 0366-7022

VL - 41

SP - 913

EP - 914

JO - Chemistry Letters

JF - Chemistry Letters

IS - 9

ER -

Electrophilic aromatic substitution of arenes with CO ₂ mediated by R3SiB(C ₆F ₅) ₄

Abstract

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