Enantioselective synthesis of a mealybug pheromone with an irregular monoterpenoid skeleton

Kosuke Hashimoto; Akira Morita; Shigefumi Kuwahara

doi:10.1021/jo801147c

Enantioselective synthesis of a mealybug pheromone with an irregular monoterpenoid skeleton

Kosuke Hashimoto, Akira Morita, Shigefumi Kuwahara

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

(Chemical Equation Presented) The first enantioselective synthesis of a mealybug sex pheromone with an unprecedented monoterpenoid skeleton has been accomplished by using a highly diastereoselective conjugate addition of an organocopper reagent to a γ-alkyl-α,β-unsaturated ester intermediate as the key step.

Original language	English
Pages (from-to)	6913-6915
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	73
Issue number	17
DOIs	https://doi.org/10.1021/jo801147c
Publication status	Published - 2008 Sept 5

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo801147c

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title = "Enantioselective synthesis of a mealybug pheromone with an irregular monoterpenoid skeleton",

abstract = "(Chemical Equation Presented) The first enantioselective synthesis of a mealybug sex pheromone with an unprecedented monoterpenoid skeleton has been accomplished by using a highly diastereoselective conjugate addition of an organocopper reagent to a γ-alkyl-α,β-unsaturated ester intermediate as the key step.",

author = "Kosuke Hashimoto and Akira Morita and Shigefumi Kuwahara",

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AU - Morita, Akira

AU - Kuwahara, Shigefumi

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AB - (Chemical Equation Presented) The first enantioselective synthesis of a mealybug sex pheromone with an unprecedented monoterpenoid skeleton has been accomplished by using a highly diastereoselective conjugate addition of an organocopper reagent to a γ-alkyl-α,β-unsaturated ester intermediate as the key step.

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Enantioselective synthesis of a mealybug pheromone with an irregular monoterpenoid skeleton

Abstract

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