TY - JOUR
T1 - Enantioselective synthesis of (+)-decarestrictine L from (2E,5E)- dibenzyloxy-2,5-heptadien-4-ol
AU - Esumi, Tomoyuki
AU - Kimura, Rieko
AU - Mori, Masako
AU - Iwabuchi, Yoshiharu
AU - Irie, Hiroshi
AU - Hatakeyama, Susumi
PY - 2000/2/1
Y1 - 2000/2/1
N2 - (+)-Decarestrictine L has been synthesized in enantiomerically pure form from (3R,4S)-1-benzyloxy-6-heptene-3,4-diol, prepared from (2E,5E)-1,7- dibenzyloxy-2,5-heptadien-4-ol, employing either Me2AlCl promoted methylative cleavage of (1R,5R,6S)-6-benzyloxy-2,9-dioxabicyclo[3.3.1]nonane or DIBAH promoted reductive cleavage of (1R,5R,6S)-6-benzyloxy-1-methyl-2,9- dioxabicyclo[3.3.1]nonane for the construction of the substituted pyran ring system.
AB - (+)-Decarestrictine L has been synthesized in enantiomerically pure form from (3R,4S)-1-benzyloxy-6-heptene-3,4-diol, prepared from (2E,5E)-1,7- dibenzyloxy-2,5-heptadien-4-ol, employing either Me2AlCl promoted methylative cleavage of (1R,5R,6S)-6-benzyloxy-2,9-dioxabicyclo[3.3.1]nonane or DIBAH promoted reductive cleavage of (1R,5R,6S)-6-benzyloxy-1-methyl-2,9- dioxabicyclo[3.3.1]nonane for the construction of the substituted pyran ring system.
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U2 - 10.3987/com-99-s60
DO - 10.3987/com-99-s60
M3 - Article
AN - SCOPUS:0034143393
SN - 0385-5414
VL - 52
SP - 525
EP - 528
JO - Heterocycles
JF - Heterocycles
IS - 2
ER -