Energy transfer from Sn2+ to RE3+ cations in ZnOP2O5 glass

Hirokazu Masai; Yusuke Hino; Takayuki Yanagida; Yutaka Fujimoto; Toshinobu Yoko

doi:10.1246/bcsj.20130281

Energy transfer from Sn2+ to RE3+ cations in ZnOP2O5 glass

Hirokazu Masai, Yusuke Hino, Takayuki Yanagida, Yutaka Fujimoto, Toshinobu Yoko

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The photoluminescence (PL) properties of rare earth (RE)-doped SnO-ZnO-P2O5 (RE-SZP) glass were examined in the visible region. RE-SZP glass, except for those doped with Ce3+, exhibited similar optical band edges because of the s-p transition in Sn2+. The RE3+ PL excitation bands in RE-SZP glass were red-shifted compared to the bands in Sn-free glass because of the energy transfer from the Sn2+ center. In addition, the emission intensity in a few RE-SZP glass systems was remarkably enhanced by Sn2+ addition. Emission decays of Sn2+ in the glass were typically independent of the RE3+, and suggest the exchange interaction between Sn2+ and RE3+. This indicated that the RE3+ cation is generally located close to the Sn2+ center in order to allow energy transfer.

Original language	English
Pages (from-to)	556-563
Number of pages	8
Journal	Bulletin of the Chemical Society of Japan
Volume	87
Issue number	4
DOIs	https://doi.org/10.1246/bcsj.20130281
Publication status	Published - 2014 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Energy transfer from Sn2+ to RE3+ cations in ZnOP2O5 glass",

abstract = "The photoluminescence (PL) properties of rare earth (RE)-doped SnO-ZnO-P2O5 (RE-SZP) glass were examined in the visible region. RE-SZP glass, except for those doped with Ce3+, exhibited similar optical band edges because of the s-p transition in Sn2+. The RE3+ PL excitation bands in RE-SZP glass were red-shifted compared to the bands in Sn-free glass because of the energy transfer from the Sn2+ center. In addition, the emission intensity in a few RE-SZP glass systems was remarkably enhanced by Sn2+ addition. Emission decays of Sn2+ in the glass were typically independent of the RE3+, and suggest the exchange interaction between Sn2+ and RE3+. This indicated that the RE3+ cation is generally located close to the Sn2+ center in order to allow energy transfer.",

author = "Hirokazu Masai and Yusuke Hino and Takayuki Yanagida and Yutaka Fujimoto and Toshinobu Yoko",

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T1 - Energy transfer from Sn2+ to RE3+ cations in ZnOP2O5 glass

AU - Masai, Hirokazu

AU - Hino, Yusuke

AU - Yanagida, Takayuki

AU - Fujimoto, Yutaka

AU - Yoko, Toshinobu

PY - 2014/1/1

Y1 - 2014/1/1

N2 - The photoluminescence (PL) properties of rare earth (RE)-doped SnO-ZnO-P2O5 (RE-SZP) glass were examined in the visible region. RE-SZP glass, except for those doped with Ce3+, exhibited similar optical band edges because of the s-p transition in Sn2+. The RE3+ PL excitation bands in RE-SZP glass were red-shifted compared to the bands in Sn-free glass because of the energy transfer from the Sn2+ center. In addition, the emission intensity in a few RE-SZP glass systems was remarkably enhanced by Sn2+ addition. Emission decays of Sn2+ in the glass were typically independent of the RE3+, and suggest the exchange interaction between Sn2+ and RE3+. This indicated that the RE3+ cation is generally located close to the Sn2+ center in order to allow energy transfer.

AB - The photoluminescence (PL) properties of rare earth (RE)-doped SnO-ZnO-P2O5 (RE-SZP) glass were examined in the visible region. RE-SZP glass, except for those doped with Ce3+, exhibited similar optical band edges because of the s-p transition in Sn2+. The RE3+ PL excitation bands in RE-SZP glass were red-shifted compared to the bands in Sn-free glass because of the energy transfer from the Sn2+ center. In addition, the emission intensity in a few RE-SZP glass systems was remarkably enhanced by Sn2+ addition. Emission decays of Sn2+ in the glass were typically independent of the RE3+, and suggest the exchange interaction between Sn2+ and RE3+. This indicated that the RE3+ cation is generally located close to the Sn2+ center in order to allow energy transfer.

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JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

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ER -

Energy transfer from Sn2+ to RE3+ cations in ZnOP2O5 glass

Abstract

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