Equilibrium state and crystal growth of (BEDT-TTF)2I3

Noriyuki Yoshimoto; Katsushi Hashimoto; Masahito Yoshizawa

doi:10.1007/BF00753945

Equilibrium state and crystal growth of (BEDT-TTF)₂I₃

Noriyuki Yoshimoto, Katsushi Hashimoto, Masahito Yoshizawa

SCI - Physics

Iwate University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The equilibrium state and crystal growth of (BEDT-TTF)₂I₃ were investigated. Measurements of the temperature dependence of solubility and analyses of the components in the solution were carried out. The analysis of the solution showed that the crystals decompose into neutral BEDT-TTF and I₂ molecules. As to the polymorphism, it was clarified that the β-form is more stable than the α-form in the temperature region between 0 and 50°C. Using these information, we succeed in growing single crystals form BEDT-TTF and I₂ and in control of the crystallizing polymorph. The polymorphic behavior was explained in terms of supersaturation as a driving force of crystal growth.

Original language	English
Pages (from-to)	1709-1714
Number of pages	6
Journal	Journal of Low Temperature Physics
Volume	105
Issue number	5-6
DOIs	https://doi.org/10.1007/BF00753945
Publication status	Published - 1996

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title = "Equilibrium state and crystal growth of (BEDT-TTF)2I3",

abstract = "The equilibrium state and crystal growth of (BEDT-TTF)2I3 were investigated. Measurements of the temperature dependence of solubility and analyses of the components in the solution were carried out. The analysis of the solution showed that the crystals decompose into neutral BEDT-TTF and I2 molecules. As to the polymorphism, it was clarified that the β-form is more stable than the α-form in the temperature region between 0 and 50°C. Using these information, we succeed in growing single crystals form BEDT-TTF and I2 and in control of the crystallizing polymorph. The polymorphic behavior was explained in terms of supersaturation as a driving force of crystal growth.",

author = "Noriyuki Yoshimoto and Katsushi Hashimoto and Masahito Yoshizawa",

year = "1996",

doi = "10.1007/BF00753945",

language = "English",

volume = "105",

pages = "1709--1714",

journal = "Journal of Low Temperature Physics",

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T1 - Equilibrium state and crystal growth of (BEDT-TTF)2I3

AU - Yoshimoto, Noriyuki

AU - Hashimoto, Katsushi

AU - Yoshizawa, Masahito

PY - 1996

Y1 - 1996

N2 - The equilibrium state and crystal growth of (BEDT-TTF)2I3 were investigated. Measurements of the temperature dependence of solubility and analyses of the components in the solution were carried out. The analysis of the solution showed that the crystals decompose into neutral BEDT-TTF and I2 molecules. As to the polymorphism, it was clarified that the β-form is more stable than the α-form in the temperature region between 0 and 50°C. Using these information, we succeed in growing single crystals form BEDT-TTF and I2 and in control of the crystallizing polymorph. The polymorphic behavior was explained in terms of supersaturation as a driving force of crystal growth.

AB - The equilibrium state and crystal growth of (BEDT-TTF)2I3 were investigated. Measurements of the temperature dependence of solubility and analyses of the components in the solution were carried out. The analysis of the solution showed that the crystals decompose into neutral BEDT-TTF and I2 molecules. As to the polymorphism, it was clarified that the β-form is more stable than the α-form in the temperature region between 0 and 50°C. Using these information, we succeed in growing single crystals form BEDT-TTF and I2 and in control of the crystallizing polymorph. The polymorphic behavior was explained in terms of supersaturation as a driving force of crystal growth.

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EP - 1714

JO - Journal of Low Temperature Physics

JF - Journal of Low Temperature Physics

IS - 5-6

ER -

Equilibrium state and crystal growth of (BEDT-TTF)₂I₃

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