Photodissociation of Mg+-CH3l has been studied in the UV region using a reflectron time-of-flight mass spectrometer. Three bands were observed in a dissociation spectrum peaking at about 27200, 29600, and 38100 cm-1, which were assigned to the bands originating from 2P←2S transition of Mg+. Five kinds of ions, CH3+, Mg+, I+, CH3I+, and Mgl+, were observed as fragment ions. Dissociation processes were discussed from the consideration of potential energy curves including charge transfer states obtained by CIS calculation.
|Title of host publication||Clusters and Nano-Assemblies|
|Subtitle of host publication||Physical and Biological Systems: Richmond, Virginia, U.S.A., 10-13 November, 2003|
|Publisher||World Scientific Publishing Co.|
|Number of pages||7|
|ISBN (Print)||9812563318, 9789812563316|
|Publication status||Published - 2005 Jan 1|