Excited state charge transfer and dissociation of Mg+-CH3I complex

Fuminori Misaizu; Ari Furuya; Hironori Tsunoyama; Koichi Ohno

doi:10.1142/9789812701879_0012

Excited state charge transfer and dissociation of Mg⁺-CH₃I complex

Fuminori Misaizu, Ari Furuya, Hironori Tsunoyama, Koichi Ohno

SCI - Chemistry

Tohoku University

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

Photodissociation of Mg⁺-CH₃l has been studied in the UV region using a reflectron time-of-flight mass spectrometer. Three bands were observed in a dissociation spectrum peaking at about 27200, 29600, and 38100 cm^-1, which were assigned to the bands originating from ²P←2^S transition of Mg⁺. Five kinds of ions, CH₃⁺, Mg⁺, I⁺, CH₃I⁺, and Mgl⁺, were observed as fragment ions. Dissociation processes were discussed from the consideration of potential energy curves including charge transfer states obtained by CIS calculation.

Original language	English
Title of host publication	Clusters and Nano-Assemblies
Subtitle of host publication	Physical and Biological Systems: Richmond, Virginia, U.S.A., 10-13 November, 2003
Publisher	World Scientific Publishing Co.
Pages	89-95
Number of pages	7
ISBN (Electronic)	9789812701879
ISBN (Print)	9812563318, 9789812563316
DOIs	https://doi.org/10.1142/9789812701879_0012
Publication status	Published - 2005 Jan 1

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10.1142/9789812701879_0012

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title = "Excited state charge transfer and dissociation of Mg+-CH3I complex",

abstract = "Photodissociation of Mg+-CH3l has been studied in the UV region using a reflectron time-of-flight mass spectrometer. Three bands were observed in a dissociation spectrum peaking at about 27200, 29600, and 38100 cm-1, which were assigned to the bands originating from 2P←2S transition of Mg+. Five kinds of ions, CH3+, Mg+, I+, CH3I+, and Mgl+, were observed as fragment ions. Dissociation processes were discussed from the consideration of potential energy curves including charge transfer states obtained by CIS calculation.",

author = "Fuminori Misaizu and Ari Furuya and Hironori Tsunoyama and Koichi Ohno",

year = "2005",

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doi = "10.1142/9789812701879_0012",

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Excited state charge transfer and dissociation of Mg⁺-CH₃I complex. / Misaizu, Fuminori; Furuya, Ari; Tsunoyama, Hironori et al.
Clusters and Nano-Assemblies: Physical and Biological Systems: Richmond, Virginia, U.S.A., 10-13 November, 2003. World Scientific Publishing Co., 2005. p. 89-95.

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

TY - CHAP

T1 - Excited state charge transfer and dissociation of Mg+-CH3I complex

AU - Misaizu, Fuminori

AU - Furuya, Ari

AU - Tsunoyama, Hironori

AU - Ohno, Koichi

PY - 2005/1/1

Y1 - 2005/1/1

N2 - Photodissociation of Mg+-CH3l has been studied in the UV region using a reflectron time-of-flight mass spectrometer. Three bands were observed in a dissociation spectrum peaking at about 27200, 29600, and 38100 cm-1, which were assigned to the bands originating from 2P←2S transition of Mg+. Five kinds of ions, CH3+, Mg+, I+, CH3I+, and Mgl+, were observed as fragment ions. Dissociation processes were discussed from the consideration of potential energy curves including charge transfer states obtained by CIS calculation.

AB - Photodissociation of Mg+-CH3l has been studied in the UV region using a reflectron time-of-flight mass spectrometer. Three bands were observed in a dissociation spectrum peaking at about 27200, 29600, and 38100 cm-1, which were assigned to the bands originating from 2P←2S transition of Mg+. Five kinds of ions, CH3+, Mg+, I+, CH3I+, and Mgl+, were observed as fragment ions. Dissociation processes were discussed from the consideration of potential energy curves including charge transfer states obtained by CIS calculation.

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BT - Clusters and Nano-Assemblies

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ER -

Excited state charge transfer and dissociation of Mg⁺-CH₃I complex

Abstract

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