Fabrication of calixarene derivative optical device by using two-photon-absorbed photopolymerization (II)

Jiro Ishihara; Kyouji Komatsu; Okihiro Sugihara; Toshikuni Kaino

Fabrication of calixarene derivative optical device by using two-photon-absorbed photopolymerization (II)

Jiro Ishihara, Kyouji Komatsu, Okihiro Sugihara, Toshikuni Kaino

Institute of Multidisciplinary Research for Advanced Materials (IMRAM)

Research output: Contribution to conference › Paper › peer-review

Abstract

Generally, optical polymer waveguides have been fabricated by using a combination of photolithography and reaction ion etching. However those processes require much time and effort. Here, we propose two-photon-absorbed photopolymerization for waveguide fabrication because thistechnique will make it possible to polymerize monomer. As comonomers p-tert-Buthylclix[8]areneacrylate (CA-Ac) and Pentaerythritoltriacrylate (PETA) (molar ratio: CA-Ac : PETA= 1:1) were used. 3-(2'-Benzimidazolyl)-7-Diethylamino-coumarin (BIDC) as a photosensitizer and Diphenyliodoniumhexafluorophosphate (DIHP) as a photo-initiator were also used. The mixed PMMA and chloroform solution of those were cast on a substrate. Focused 800nm femtosecond pulsed laser beam by objective lens was scanned perpendicularly to the substrate. Thus we obtained a 3D polymer waveguide and confirmed the confinement of a 1300nm wavelength light.

Original language	English
Pages	4398-4399
Number of pages	2
Publication status	Published - 2005 Dec 1
Event	54th SPSJ Symposium on Macromolecules - Yamagata, Japan Duration: 2005 Sept 20 → 2005 Sept 22

Other

Other	54th SPSJ Symposium on Macromolecules
Country/Territory	Japan
City	Yamagata
Period	05/9/20 → 05/9/22

Keywords

Calixarene
Femto-second laserlithography
Optical waveguide
Two-photon-absorption

ASJC Scopus subject areas

Engineering(all)

Cite this

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title = "Fabrication of calixarene derivative optical device by using two-photon-absorbed photopolymerization (II)",

abstract = "Generally, optical polymer waveguides have been fabricated by using a combination of photolithography and reaction ion etching. However those processes require much time and effort. Here, we propose two-photon-absorbed photopolymerization for waveguide fabrication because thistechnique will make it possible to polymerize monomer. As comonomers p-tert-Buthylclix[8]areneacrylate (CA-Ac) and Pentaerythritoltriacrylate (PETA) (molar ratio: CA-Ac : PETA= 1:1) were used. 3-(2'-Benzimidazolyl)-7-Diethylamino-coumarin (BIDC) as a photosensitizer and Diphenyliodoniumhexafluorophosphate (DIHP) as a photo-initiator were also used. The mixed PMMA and chloroform solution of those were cast on a substrate. Focused 800nm femtosecond pulsed laser beam by objective lens was scanned perpendicularly to the substrate. Thus we obtained a 3D polymer waveguide and confirmed the confinement of a 1300nm wavelength light.",

keywords = "Calixarene, Femto-second laserlithography, Optical waveguide, Two-photon-absorption",

author = "Jiro Ishihara and Kyouji Komatsu and Okihiro Sugihara and Toshikuni Kaino",

year = "2005",

month = dec,

day = "1",

language = "English",

pages = "4398--4399",

note = "54th SPSJ Symposium on Macromolecules ; Conference date: 20-09-2005 Through 22-09-2005",

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T1 - Fabrication of calixarene derivative optical device by using two-photon-absorbed photopolymerization (II)

AU - Ishihara, Jiro

AU - Komatsu, Kyouji

AU - Sugihara, Okihiro

AU - Kaino, Toshikuni

PY - 2005/12/1

Y1 - 2005/12/1

N2 - Generally, optical polymer waveguides have been fabricated by using a combination of photolithography and reaction ion etching. However those processes require much time and effort. Here, we propose two-photon-absorbed photopolymerization for waveguide fabrication because thistechnique will make it possible to polymerize monomer. As comonomers p-tert-Buthylclix[8]areneacrylate (CA-Ac) and Pentaerythritoltriacrylate (PETA) (molar ratio: CA-Ac : PETA= 1:1) were used. 3-(2'-Benzimidazolyl)-7-Diethylamino-coumarin (BIDC) as a photosensitizer and Diphenyliodoniumhexafluorophosphate (DIHP) as a photo-initiator were also used. The mixed PMMA and chloroform solution of those were cast on a substrate. Focused 800nm femtosecond pulsed laser beam by objective lens was scanned perpendicularly to the substrate. Thus we obtained a 3D polymer waveguide and confirmed the confinement of a 1300nm wavelength light.

AB - Generally, optical polymer waveguides have been fabricated by using a combination of photolithography and reaction ion etching. However those processes require much time and effort. Here, we propose two-photon-absorbed photopolymerization for waveguide fabrication because thistechnique will make it possible to polymerize monomer. As comonomers p-tert-Buthylclix[8]areneacrylate (CA-Ac) and Pentaerythritoltriacrylate (PETA) (molar ratio: CA-Ac : PETA= 1:1) were used. 3-(2'-Benzimidazolyl)-7-Diethylamino-coumarin (BIDC) as a photosensitizer and Diphenyliodoniumhexafluorophosphate (DIHP) as a photo-initiator were also used. The mixed PMMA and chloroform solution of those were cast on a substrate. Focused 800nm femtosecond pulsed laser beam by objective lens was scanned perpendicularly to the substrate. Thus we obtained a 3D polymer waveguide and confirmed the confinement of a 1300nm wavelength light.

KW - Calixarene

KW - Femto-second laserlithography

KW - Optical waveguide

KW - Two-photon-absorption

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M3 - Paper

AN - SCOPUS:33645572749

SP - 4398

EP - 4399

T2 - 54th SPSJ Symposium on Macromolecules

Y2 - 20 September 2005 through 22 September 2005

ER -

Fabrication of calixarene derivative optical device by using two-photon-absorbed photopolymerization (II)

Abstract

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Keywords

ASJC Scopus subject areas

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