Fabrication of nanoporous copper by dealloying of amorphous Ti-Cu-Ag alloys

Zhenhua Dan, Fengxiang Qin, Akihiro Makino, Yu Sugawara, Izumi Muto, Nobuyoshi Hara

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40 Citations (Scopus)


Ternary TiCuAg amorphous alloys were used as the starting materials for fabricating nanoporous copper (NPC) in HF solutions. NPC with a pore size of 8-55 nm was fabricated through dealloying from an amorphous Ti 60Cu40-xAgx (x = 1, 2 at.%) ribbon alloy under free immersion conditions. A 3-dimensional bicontinuous NPC structure formed on Ti60Cu40, Ti60Cu 39Ag1, and Ti60Cu38Ag2 ribbon alloys with pore sizes of 130 nm, 48 nm, and 55 nm, respectively, after immersion in 0.13 M HF solution for 43.2 ks. The pore sizes of dealloyed ribbon alloys in 0.03 M HF solution were confirmed to be 71 nm, 41 nm and 39 nm, respectively. The pore size of NPCs dealloyed from Ag-added alloys was smaller than that of the Ti-Cu alloy. Smaller pores formed in the beginning of dealloying because even distributed Ag atoms in amorphous precursors suppressed the diffusion of Cu adatoms. The final characteristic pore size showed a weak dependence on the solution concentrations. Diffusivity decreased more than two orders due to the alloying of Ag. The dealloying residue was fcc Cu-Ag and Ag, with Ag adatoms concentrated at the grain boundary. The uneven distribution of Ag atoms caused the coarsening of nanoporous Cu after the prolonged dealloying.

Original languageEnglish
Pages (from-to)S134-S138
JournalJournal of Alloys and Compounds
Issue numberSUPPL. 1
Publication statusPublished - 2014


  • Amorphous materials
  • Corrosion
  • Dealloying
  • Diffusion
  • Nanoporous copper
  • Transmission electron microscopy


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