Abstract
N-Unsubstituted indazoles 3 and 1-arylindazoles 4 are readily available in good to high yields through [3+2] cycloaddition of 2-(trimethylsilyI)aryl triflates 1 and diazo compounds in the presence of KF or CsF under mild reaction conditions. Furthermore, we found that azomethine imides also underwent cycloaddition reaction with 2-(trimethylsilyl)phenyl triflates (la) in the presence of KF to afford indazolone derivatives 6 in moderate yields.
Original language | English |
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Pages (from-to) | 957-972 |
Number of pages | 16 |
Journal | Collection of Czechoslovak Chemical Communications |
Volume | 74 |
Issue number | 6 |
DOIs | |
Publication status | Published - 2009 Jun |
Keywords
- 1,3-dipolar cycloaddition
- [3+2] cycloaddition
- Arynes
- Azomethine imides
- Diazo compounds
- Indazoles