Facile isomerization of a tungsten silyl complex to a base-stabilized silylene complex via 1,2-migration of an aryl group

Masaaki Okazaki; Eiji Suzuki; Norito Miyajima; Hiromi Tobita; Hiroshi Ogino

doi:10.1021/om034106p

Facile isomerization of a tungsten silyl complex to a base-stabilized silylene complex via 1,2-migration of an aryl group

Masaaki Okazaki, Eiji Suzuki, Norito Miyajima, Hiromi Tobita, Hiroshi Ogino

IEHE - Institute for Excellence in Higher Education (organization affiliation only)

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Irradiation of Cp*(CO)₃WMe in the presence of N,N-dimethyl-2-(dimethylsilyl)aniline led to the intermediate formation of Cp*(CO)₂W{κ²(Si,N)-Me₂ N(o-C₆H₄SiMe₂)} (3), which was converted to the base-stabilized silylene complex Cp*(CO)₂W{κ² (Si,C)-SiMe₂-NMe₂(o-C₆H₄)} (2) through 1,2-migration of the aryl group.

Original language	English
Pages (from-to)	4633-4635
Number of pages	3
Journal	Organometallics
Volume	22
Issue number	23
DOIs	https://doi.org/10.1021/om034106p
Publication status	Published - 2003 Nov 10

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title = "Facile isomerization of a tungsten silyl complex to a base-stabilized silylene complex via 1,2-migration of an aryl group",

abstract = "Irradiation of Cp*(CO)3WMe in the presence of N,N-dimethyl-2-(dimethylsilyl)aniline led to the intermediate formation of Cp*(CO)2W{κ2(Si,N)-Me2 N(o-C6H4SiMe2)} (3), which was converted to the base-stabilized silylene complex Cp*(CO)2W{κ2 (Si,C)-SiMe2-NMe2(o-C6H4)} (2) through 1,2-migration of the aryl group.",

author = "Masaaki Okazaki and Eiji Suzuki and Norito Miyajima and Hiromi Tobita and Hiroshi Ogino",

year = "2003",

month = nov,

day = "10",

doi = "10.1021/om034106p",

language = "English",

volume = "22",

pages = "4633--4635",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "23",

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TY - JOUR

T1 - Facile isomerization of a tungsten silyl complex to a base-stabilized silylene complex via 1,2-migration of an aryl group

AU - Okazaki, Masaaki

AU - Suzuki, Eiji

AU - Miyajima, Norito

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 2003/11/10

Y1 - 2003/11/10

N2 - Irradiation of Cp*(CO)3WMe in the presence of N,N-dimethyl-2-(dimethylsilyl)aniline led to the intermediate formation of Cp*(CO)2W{κ2(Si,N)-Me2 N(o-C6H4SiMe2)} (3), which was converted to the base-stabilized silylene complex Cp*(CO)2W{κ2 (Si,C)-SiMe2-NMe2(o-C6H4)} (2) through 1,2-migration of the aryl group.

AB - Irradiation of Cp*(CO)3WMe in the presence of N,N-dimethyl-2-(dimethylsilyl)aniline led to the intermediate formation of Cp*(CO)2W{κ2(Si,N)-Me2 N(o-C6H4SiMe2)} (3), which was converted to the base-stabilized silylene complex Cp*(CO)2W{κ2 (Si,C)-SiMe2-NMe2(o-C6H4)} (2) through 1,2-migration of the aryl group.

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U2 - 10.1021/om034106p

DO - 10.1021/om034106p

M3 - Article

AN - SCOPUS:0345015871

SN - 0276-7333

VL - 22

SP - 4633

EP - 4635

JO - Organometallics

JF - Organometallics

IS - 23

ER -

Facile isomerization of a tungsten silyl complex to a base-stabilized silylene complex via 1,2-migration of an aryl group

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