Far-wing excitation study on the fine-structure transition of Hg( 3P1-3P0) in collisions with N 2

Kenji Ohmori; Takahiro Kurosawa; Hisashi Chiba; Misaki Okunishi; Yukinori Sato

doi:10.1063/1.467153

Far-wing excitation study on the fine-structure transition of Hg( ³P₁-³P₀) in collisions with N ₂

Kenji Ohmori, Takahiro Kurosawa, Hisashi Chiba, Misaki Okunishi, Yukinori Sato

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Abstract

Measurements are made of the far-wing excitation spectra of HgN₂ collisional quasimolecules for the production of Hg*(³P ₀) and Hg*(³P₁) in the vicinity of the Hg resonance line. It is found that the A-X excitation is by far more effective in producing Hg*(³P₀) than the B-X excitation. This is contrary to the case of bound-bound excitation of the HgN₂ van der Waals complex [C. Jouvet and B. Soep, J. Chem. Phys. 81, 2229 (1984); Fuke et al., ibid. 86, 4745 (1987); Yamanouchi et al., ibid. 89, 2975 (1988)].

Original language	English
Pages (from-to)	5381-5383
Number of pages	3
Journal	The Journal of Chemical Physics
Volume	100
Issue number	7
DOIs	https://doi.org/10.1063/1.467153
Publication status	Published - 1994
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Far-wing excitation study on the fine-structure transition of Hg( 3P1-3P0) in collisions with N 2",

abstract = "Measurements are made of the far-wing excitation spectra of HgN2 collisional quasimolecules for the production of Hg*(3P 0) and Hg*(3P1) in the vicinity of the Hg resonance line. It is found that the A-X excitation is by far more effective in producing Hg*(3P0) than the B-X excitation. This is contrary to the case of bound-bound excitation of the HgN2 van der Waals complex [C. Jouvet and B. Soep, J. Chem. Phys. 81, 2229 (1984); Fuke et al., ibid. 86, 4745 (1987); Yamanouchi et al., ibid. 89, 2975 (1988)].",

author = "Kenji Ohmori and Takahiro Kurosawa and Hisashi Chiba and Misaki Okunishi and Yukinori Sato",

year = "1994",

doi = "10.1063/1.467153",

language = "English",

volume = "100",

pages = "5381--5383",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

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TY - JOUR

T1 - Far-wing excitation study on the fine-structure transition of Hg( 3P1-3P0) in collisions with N 2

AU - Ohmori, Kenji

AU - Kurosawa, Takahiro

AU - Chiba, Hisashi

AU - Okunishi, Misaki

AU - Sato, Yukinori

PY - 1994

Y1 - 1994

N2 - Measurements are made of the far-wing excitation spectra of HgN2 collisional quasimolecules for the production of Hg*(3P 0) and Hg*(3P1) in the vicinity of the Hg resonance line. It is found that the A-X excitation is by far more effective in producing Hg*(3P0) than the B-X excitation. This is contrary to the case of bound-bound excitation of the HgN2 van der Waals complex [C. Jouvet and B. Soep, J. Chem. Phys. 81, 2229 (1984); Fuke et al., ibid. 86, 4745 (1987); Yamanouchi et al., ibid. 89, 2975 (1988)].

AB - Measurements are made of the far-wing excitation spectra of HgN2 collisional quasimolecules for the production of Hg*(3P 0) and Hg*(3P1) in the vicinity of the Hg resonance line. It is found that the A-X excitation is by far more effective in producing Hg*(3P0) than the B-X excitation. This is contrary to the case of bound-bound excitation of the HgN2 van der Waals complex [C. Jouvet and B. Soep, J. Chem. Phys. 81, 2229 (1984); Fuke et al., ibid. 86, 4745 (1987); Yamanouchi et al., ibid. 89, 2975 (1988)].

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DO - 10.1063/1.467153

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VL - 100

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 7

ER -

Far-wing excitation study on the fine-structure transition of Hg( ³P₁-³P₀) in collisions with N ₂

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