Ferrimagnetic property of two-dimensional layered compound K[Mn(3-MeOsalen)]2[Cr(CN)6]·H2O

Hitoshi Miyasaka, Hisashi Okawa, Naohide Matsumoto

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1 Citation (Scopus)


A series of bimetallic compounds of the general formula K[Mn(3-MeOsalen)]2[M(CN)6] (M = Co3+, Fe3+, Mn3+, Cr3+) has a similar 2-D network structure but their magnetic properties vary depending upon the nature of the metal ion of [M(CN)6]3- and the interlayer magnetic interaction. The magnetic property of K[Mn(3-MeOsalen)]2[Cr(CN)6]·H2O shows a ferrimagnetic nature arising from an intralayer ferrimagnetic ordering due to the antiferromagnetic spin arrangement of neighboring high spin Mn3+ and Cr3+, and an interlayer ferromagnetic interaction.

Original languageEnglish
Pages (from-to)1015-1023
Number of pages9
JournalMolecular Crystals and Liquid Crystals
Publication statusPublished - 1999
EventProceedings of the 1998 6th International Conference on Molecule Based Magnets (ICMM'98) - Seignosse, France
Duration: 1998 Sept 121998 Sept 17


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