First asymmetric photochemistry with nucleosides and DNA: Enantiodifferentiating Z-E photoisomerization of cyclooctene

Takehiko Wada; Norimitsu Sugahara; Mahito Kawano; Yoshihisa Inoue

doi:10.1246/cl.2000.1174

First asymmetric photochemistry with nucleosides and DNA: Enantiodifferentiating Z-E photoisomerization of cyclooctene

Takehiko Wada, Norimitsu Sugahara, Mahito Kawano, Yoshihisa Inoue

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

Thymidine and uridine, as well as calf thymus DNA (ctDNA), have been shown for the first time to function as chiral photosensitizers in aqueous solution, to effect the enantiodifferentiating photoisomerization of (Z)-cyclooctene, giving the chiral (E)-isomer in enantiomeric excesses of up to 15%.

Original language	English
Pages (from-to)	1174-1175
Number of pages	2
Journal	Chemistry Letters
Issue number	10
DOIs	https://doi.org/10.1246/cl.2000.1174
Publication status	Published - 2000
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "First asymmetric photochemistry with nucleosides and DNA: Enantiodifferentiating Z-E photoisomerization of cyclooctene",

abstract = "Thymidine and uridine, as well as calf thymus DNA (ctDNA), have been shown for the first time to function as chiral photosensitizers in aqueous solution, to effect the enantiodifferentiating photoisomerization of (Z)-cyclooctene, giving the chiral (E)-isomer in enantiomeric excesses of up to 15%.",

author = "Takehiko Wada and Norimitsu Sugahara and Mahito Kawano and Yoshihisa Inoue",

year = "2000",

doi = "10.1246/cl.2000.1174",

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T1 - First asymmetric photochemistry with nucleosides and DNA

T2 - Enantiodifferentiating Z-E photoisomerization of cyclooctene

AU - Wada, Takehiko

AU - Sugahara, Norimitsu

AU - Kawano, Mahito

AU - Inoue, Yoshihisa

PY - 2000

Y1 - 2000

N2 - Thymidine and uridine, as well as calf thymus DNA (ctDNA), have been shown for the first time to function as chiral photosensitizers in aqueous solution, to effect the enantiodifferentiating photoisomerization of (Z)-cyclooctene, giving the chiral (E)-isomer in enantiomeric excesses of up to 15%.

AB - Thymidine and uridine, as well as calf thymus DNA (ctDNA), have been shown for the first time to function as chiral photosensitizers in aqueous solution, to effect the enantiodifferentiating photoisomerization of (Z)-cyclooctene, giving the chiral (E)-isomer in enantiomeric excesses of up to 15%.

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DO - 10.1246/cl.2000.1174

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First asymmetric photochemistry with nucleosides and DNA: Enantiodifferentiating Z-E photoisomerization of cyclooctene

Abstract

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