First determination of the absolute stereochemistry of a naturally occurring 1,1′-biphenanthrene, (−)-blestriarene C, and its unexpected photoracemization

Tetsutaro Hattori; Yuhi Shimazumi; Osamu Yamabe; Eiji Koshiishi; Sotaro Miyano

doi:10.1039/b207517b

First determination of the absolute stereochemistry of a naturally occurring 1,1′-biphenanthrene, (−)-blestriarene C, and its unexpected photoracemization

Tetsutaro Hattori, Yuhi Shimazumi, Osamu Yamabe, Eiji Koshiishi, Sotaro Miyano

ENG - Biomolecular Engineering

Tohoku University

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A naturally occurring 1,1′-biphenanthrene, blestriarene C, was prepared and its absolute stereochemistry was determined to be S _a-(−) by an empirical method, during which the compound was found to undergo rapid photoracemization even under ambient light exposure.

Original language	English
Pages (from-to)	2234-2235
Number of pages	2
Journal	Chemical Communications
Volume	2
Issue number	19
DOIs	https://doi.org/10.1039/b207517b
Publication status	Published - 2002

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10.1039/b207517b

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title = "First determination of the absolute stereochemistry of a naturally occurring 1,1′-biphenanthrene, (−)-blestriarene C, and its unexpected photoracemization",

abstract = "A naturally occurring 1,1′-biphenanthrene, blestriarene C, was prepared and its absolute stereochemistry was determined to be S a-(−) by an empirical method, during which the compound was found to undergo rapid photoracemization even under ambient light exposure.",

author = "Tetsutaro Hattori and Yuhi Shimazumi and Osamu Yamabe and Eiji Koshiishi and Sotaro Miyano",

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T1 - First determination of the absolute stereochemistry of a naturally occurring 1,1′-biphenanthrene, (−)-blestriarene C, and its unexpected photoracemization

AU - Hattori, Tetsutaro

AU - Shimazumi, Yuhi

AU - Yamabe, Osamu

AU - Koshiishi, Eiji

AU - Miyano, Sotaro

PY - 2002

Y1 - 2002

N2 - A naturally occurring 1,1′-biphenanthrene, blestriarene C, was prepared and its absolute stereochemistry was determined to be S a-(−) by an empirical method, during which the compound was found to undergo rapid photoracemization even under ambient light exposure.

AB - A naturally occurring 1,1′-biphenanthrene, blestriarene C, was prepared and its absolute stereochemistry was determined to be S a-(−) by an empirical method, during which the compound was found to undergo rapid photoracemization even under ambient light exposure.

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DO - 10.1039/b207517b

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AN - SCOPUS:0036397641

SN - 1359-7345

VL - 2

SP - 2234

EP - 2235

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

First determination of the absolute stereochemistry of a naturally occurring 1,1′-biphenanthrene, (−)-blestriarene C, and its unexpected photoracemization

Abstract

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