Formation and reactions of stabilized [2,4-Di-t-butyl-6-(methylthiomethyl)phenyl]thioxophosphine

Kazunori Kamijo; Kozo Toyota; Masaaki Yoshifuji

doi:10.1246/cl.1999.567

Formation and reactions of stabilized [2,4-Di-t-butyl-6-(methylthiomethyl)phenyl]thioxophosphine

Kazunori Kamijo, Kozo Toyota, Masaaki Yoshifuji

SCI - Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

A stabilized thioxophosphine bearing the 2,4-di-t-butyl-6-(methylthiomethyl)phenyl group was generated either by reaction of the corresponding phosphonous dichloride with bis(trimethylsilyl) sulfide or by desulfurization reaction of the corresponding dithioxophosphorane using tris(dimethyl-amino)phosphine. The thioxophosphine, thus generated was trimerized to trithiatriphosphinane.

Original language	English
Pages (from-to)	567-568
Number of pages	2
Journal	Chemistry Letters
Issue number	7
DOIs	https://doi.org/10.1246/cl.1999.567
Publication status	Published - 1999

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abstract = "A stabilized thioxophosphine bearing the 2,4-di-t-butyl-6-(methylthiomethyl)phenyl group was generated either by reaction of the corresponding phosphonous dichloride with bis(trimethylsilyl) sulfide or by desulfurization reaction of the corresponding dithioxophosphorane using tris(dimethyl-amino)phosphine. The thioxophosphine, thus generated was trimerized to trithiatriphosphinane.",

author = "Kazunori Kamijo and Kozo Toyota and Masaaki Yoshifuji",

year = "1999",

doi = "10.1246/cl.1999.567",

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journal = "Chemistry Letters",

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AU - Kamijo, Kazunori

AU - Toyota, Kozo

AU - Yoshifuji, Masaaki

PY - 1999

Y1 - 1999

N2 - A stabilized thioxophosphine bearing the 2,4-di-t-butyl-6-(methylthiomethyl)phenyl group was generated either by reaction of the corresponding phosphonous dichloride with bis(trimethylsilyl) sulfide or by desulfurization reaction of the corresponding dithioxophosphorane using tris(dimethyl-amino)phosphine. The thioxophosphine, thus generated was trimerized to trithiatriphosphinane.

AB - A stabilized thioxophosphine bearing the 2,4-di-t-butyl-6-(methylthiomethyl)phenyl group was generated either by reaction of the corresponding phosphonous dichloride with bis(trimethylsilyl) sulfide or by desulfurization reaction of the corresponding dithioxophosphorane using tris(dimethyl-amino)phosphine. The thioxophosphine, thus generated was trimerized to trithiatriphosphinane.

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 7

ER -

Formation and reactions of stabilized [2,4-Di-t-butyl-6-(methylthiomethyl)phenyl]thioxophosphine

Abstract

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