Formation of highly oriented graphite from poly(acrylonitrile) prepared between the lamellae of montmorillonite

Naohiro Sonobe; Takashi Kyotani; Yoshihiro Hishiyama; Minoru Shiraishi; Akira Tomita

doi:10.1021/j100335a037

Formation of highly oriented graphite from poly(acrylonitrile) prepared between the lamellae of montmorillonite

Naohiro Sonobe, Takashi Kyotani, Yoshihiro Hishiyama, Minoru Shiraishi, Akira Tomita

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

An attempt was made to prepare a carbon sample having a highly oriented structure from poly(acrylonitrile) by using a two-dimensional opening between the lamellae of montmorillonite as the field of carbonization. The carbon prepared at 700°C was liberated from montmorillonite and then it was subjected to heat treatment at various temperatures up to 2800°C. The characteristics of the resulting carbon were determined by microscopic, diffractometric, spectroscopic, and magnetoresistance methods. The graphitizability of the carbon is very high, and the carbon heat-treated at 2800°C has almost the same characteristics as the ideal graphite crystal. It consists of graphitic films with L_c value of about 40 nm and very large L_a value of more than 1 μm in many cases.

Original language	English
Pages (from-to)	7029-7034
Number of pages	6
Journal	Journal of physical chemistry
Volume	92
Issue number	24
DOIs	https://doi.org/10.1021/j100335a037
Publication status	Published - 1988 Jan 1

ASJC Scopus subject areas

Engineering(all)
Physical and Theoretical Chemistry

Access to Document

10.1021/j100335a037

Cite this

@article{eb854f354d124a93a6394ca8b315cb67,

title = "Formation of highly oriented graphite from poly(acrylonitrile) prepared between the lamellae of montmorillonite",

abstract = "An attempt was made to prepare a carbon sample having a highly oriented structure from poly(acrylonitrile) by using a two-dimensional opening between the lamellae of montmorillonite as the field of carbonization. The carbon prepared at 700°C was liberated from montmorillonite and then it was subjected to heat treatment at various temperatures up to 2800°C. The characteristics of the resulting carbon were determined by microscopic, diffractometric, spectroscopic, and magnetoresistance methods. The graphitizability of the carbon is very high, and the carbon heat-treated at 2800°C has almost the same characteristics as the ideal graphite crystal. It consists of graphitic films with Lc value of about 40 nm and very large La value of more than 1 μm in many cases.",

author = "Naohiro Sonobe and Takashi Kyotani and Yoshihiro Hishiyama and Minoru Shiraishi and Akira Tomita",

year = "1988",

month = jan,

day = "1",

doi = "10.1021/j100335a037",

language = "English",

volume = "92",

pages = "7029--7034",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "24",

}

TY - JOUR

T1 - Formation of highly oriented graphite from poly(acrylonitrile) prepared between the lamellae of montmorillonite

AU - Sonobe, Naohiro

AU - Kyotani, Takashi

AU - Hishiyama, Yoshihiro

AU - Shiraishi, Minoru

AU - Tomita, Akira

PY - 1988/1/1

Y1 - 1988/1/1

N2 - An attempt was made to prepare a carbon sample having a highly oriented structure from poly(acrylonitrile) by using a two-dimensional opening between the lamellae of montmorillonite as the field of carbonization. The carbon prepared at 700°C was liberated from montmorillonite and then it was subjected to heat treatment at various temperatures up to 2800°C. The characteristics of the resulting carbon were determined by microscopic, diffractometric, spectroscopic, and magnetoresistance methods. The graphitizability of the carbon is very high, and the carbon heat-treated at 2800°C has almost the same characteristics as the ideal graphite crystal. It consists of graphitic films with Lc value of about 40 nm and very large La value of more than 1 μm in many cases.

AB - An attempt was made to prepare a carbon sample having a highly oriented structure from poly(acrylonitrile) by using a two-dimensional opening between the lamellae of montmorillonite as the field of carbonization. The carbon prepared at 700°C was liberated from montmorillonite and then it was subjected to heat treatment at various temperatures up to 2800°C. The characteristics of the resulting carbon were determined by microscopic, diffractometric, spectroscopic, and magnetoresistance methods. The graphitizability of the carbon is very high, and the carbon heat-treated at 2800°C has almost the same characteristics as the ideal graphite crystal. It consists of graphitic films with Lc value of about 40 nm and very large La value of more than 1 μm in many cases.

UR - http://www.scopus.com/inward/record.url?scp=0024142578&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0024142578&partnerID=8YFLogxK

U2 - 10.1021/j100335a037

DO - 10.1021/j100335a037

M3 - Article

AN - SCOPUS:0024142578

SN - 0022-3654

VL - 92

SP - 7029

EP - 7034

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 24

ER -

Formation of highly oriented graphite from poly(acrylonitrile) prepared between the lamellae of montmorillonite

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this