TY - JOUR
T1 - Formation of strong OH2⋯-O2C hydrogen bonds in a trinuclear core-based nickel 1,3,5-benzenetricarboxylate coordination polymer
AU - Noro, Shin Ichiro
AU - Akutagawa, Tomoyuki
AU - Nakamura, Takayoshi
PY - 2007/6
Y1 - 2007/6
N2 - The nickel 1,3,5-benzenetricarboxylate (1,3,5-btc3-) coordination polymer, [Ni6(μ-OH2)4(1,3,5- btc)4(H2O)12]n (1), has been synthesized using a hydrothermal reaction. Trinuclear nickel cores constructed from the μ-OH2 and carboxylate bridges are linked by the 1,3,5-btc3- ligands, forming a two-dimensional network. The μ-OH2 molecules form strong hydrogen bonds with the free oxygens of the carboxylate groups in the trinuclear clusters. A structural phase transition occurs around 373 K and is categorized as a second-order phase transition.
AB - The nickel 1,3,5-benzenetricarboxylate (1,3,5-btc3-) coordination polymer, [Ni6(μ-OH2)4(1,3,5- btc)4(H2O)12]n (1), has been synthesized using a hydrothermal reaction. Trinuclear nickel cores constructed from the μ-OH2 and carboxylate bridges are linked by the 1,3,5-btc3- ligands, forming a two-dimensional network. The μ-OH2 molecules form strong hydrogen bonds with the free oxygens of the carboxylate groups in the trinuclear clusters. A structural phase transition occurs around 373 K and is categorized as a second-order phase transition.
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U2 - 10.1021/cg060819+
DO - 10.1021/cg060819+
M3 - Article
AN - SCOPUS:34347250903
SN - 1528-7483
VL - 7
SP - 1205
EP - 1208
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 6
ER -